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Controls on the Presence, Concentration, Storage, and Variability of Soil Inorganic Carbon in a Semi-arid Watershed

Controls on the Presence, Concentration, Storage, and Variability of Soil Inorganic Carbon in a Semi-arid Watershed PDF Author: Christopher Allen Stanbery
Publisher:
ISBN:
Category : Soils
Languages : en
Pages : 69

Book Description
"Soil inorganic carbon (SIC) constitutes approximately 40% of terrestrial soil carbon and is an integral part of the global carbon cycle; however, the controls on the storage and flux of inorganic carbon are poorly understood. Soil forming factors controlling SIC storage and flux include climate, organisms, relief, parent material, and time (Jenny, 1941). Rainfall is a primary factor controlling SIC accumulation in arid and semi-arid regions, but the hierarchy of controls on SIC development is complex. The Reynolds Creek Experimental Watershed in southwestern Idaho is an ideal location to study factors influencing SIC, as the carbon pool transitions from predominately inorganic carbon in the lower elevations, to organic carbon at higher elevations. This study builds upon fundamental studies in soil science that define and describe precipitation controls on the 'pedocal' (calcic) to 'pedalfer' (non-calcic) soil transition (e.g. Marbut, 1935; Jenny, 1941) by both defining the precipitation boundary in Reynolds Creek, and quantifying the amount of carbon storage within calcic soils. We collected soil samples from soils developed under a wide range of soil-forming regimes: 1) along a precipitation gradient, 2) within different vegetation communities (sagebrush species (Artimesia spp), bitterbrush (Purshia tridentata), greasewood (Sarcobatus vermiculatus), and juniper (Juniperus occidentalis)) 3) from different parent materials (granite, basalt, other volcanics, and alluvium) and 4) from terrace surfaces of different ages. Our results show SIC does not accumulate above a threshold of ~500 mm mean annual precipitation, and variability in SIC below that value is significant. Soil inorganic carbon content from ~1 m deep soil pits and cores at 71 sites shows that 64 sites contained less than 10 kg/m2 SIC, 5 sites contained between 10-20 kg/m2, and 2 sites had between 24 and 29 kg/m2. Random forest modeling and multiple linear regression of the environmental controls on SIC indicate that precipitation is the primary control on SIC accumulation, where increased precipitation correlates with lower amounts of SIC. Elevation is an effective predictor of SIC, as it is strongly auto-correlated with precipitation and vegetation. Parent material consistently ranks as an important predictor in random forest analysis; however, we were unable to quantify the importance of wind-blown dust in the soil profiles, which we believe plays a vital role in SIC accumulation. Despite a recognition of different stages of carbonate development and accumulation rates between gravelly and non-gravelly soils, studies often ignore carbonate coatings on gravels in measurements of soil inorganic carbon (SIC). By quantifying and differentiating the fine (2 mm) and coarse (>2 mm) fractions of SIC in the Reynolds Creek Experimental Watershed in southwestern Idaho, we show that gravel coatings contain up to 44% of total SIC at a given site. Among the 26 soil sites examined throughout the watershed, an average of 13% of the total SIC is stored as carbonate coasts within in the gravel fraction. We measured a high level of pedon-scale field variability (up to 220%) among the three faces of 1 m3 soil pits. Analytical error associated with the modified pressure calcimeter (0.001-0.014%), is considerably less than naturally occurring heterogeneities in SIC within the soil profile. This work highlights and quantifies two sources of uncertainty in studies of SIC needed to inform future research. First, in gravelly sites, the >2 mm portion of soils may store a large percentage of SIC. Second, SIC varies considerably at the pedon-scale, so studies attempting to quantify carbon storage over landscape scales need to consider this variability. This study creates a framework for understanding SIC in Reynolds Creek that may be applied to future work.."--Boise State University ScholarWorks.

Controls on the Presence, Concentration, Storage, and Variability of Soil Inorganic Carbon in a Semi-arid Watershed

Controls on the Presence, Concentration, Storage, and Variability of Soil Inorganic Carbon in a Semi-arid Watershed PDF Author: Christopher Allen Stanbery
Publisher:
ISBN:
Category : Soils
Languages : en
Pages : 69

Book Description
"Soil inorganic carbon (SIC) constitutes approximately 40% of terrestrial soil carbon and is an integral part of the global carbon cycle; however, the controls on the storage and flux of inorganic carbon are poorly understood. Soil forming factors controlling SIC storage and flux include climate, organisms, relief, parent material, and time (Jenny, 1941). Rainfall is a primary factor controlling SIC accumulation in arid and semi-arid regions, but the hierarchy of controls on SIC development is complex. The Reynolds Creek Experimental Watershed in southwestern Idaho is an ideal location to study factors influencing SIC, as the carbon pool transitions from predominately inorganic carbon in the lower elevations, to organic carbon at higher elevations. This study builds upon fundamental studies in soil science that define and describe precipitation controls on the 'pedocal' (calcic) to 'pedalfer' (non-calcic) soil transition (e.g. Marbut, 1935; Jenny, 1941) by both defining the precipitation boundary in Reynolds Creek, and quantifying the amount of carbon storage within calcic soils. We collected soil samples from soils developed under a wide range of soil-forming regimes: 1) along a precipitation gradient, 2) within different vegetation communities (sagebrush species (Artimesia spp), bitterbrush (Purshia tridentata), greasewood (Sarcobatus vermiculatus), and juniper (Juniperus occidentalis)) 3) from different parent materials (granite, basalt, other volcanics, and alluvium) and 4) from terrace surfaces of different ages. Our results show SIC does not accumulate above a threshold of ~500 mm mean annual precipitation, and variability in SIC below that value is significant. Soil inorganic carbon content from ~1 m deep soil pits and cores at 71 sites shows that 64 sites contained less than 10 kg/m2 SIC, 5 sites contained between 10-20 kg/m2, and 2 sites had between 24 and 29 kg/m2. Random forest modeling and multiple linear regression of the environmental controls on SIC indicate that precipitation is the primary control on SIC accumulation, where increased precipitation correlates with lower amounts of SIC. Elevation is an effective predictor of SIC, as it is strongly auto-correlated with precipitation and vegetation. Parent material consistently ranks as an important predictor in random forest analysis; however, we were unable to quantify the importance of wind-blown dust in the soil profiles, which we believe plays a vital role in SIC accumulation. Despite a recognition of different stages of carbonate development and accumulation rates between gravelly and non-gravelly soils, studies often ignore carbonate coatings on gravels in measurements of soil inorganic carbon (SIC). By quantifying and differentiating the fine (2 mm) and coarse (>2 mm) fractions of SIC in the Reynolds Creek Experimental Watershed in southwestern Idaho, we show that gravel coatings contain up to 44% of total SIC at a given site. Among the 26 soil sites examined throughout the watershed, an average of 13% of the total SIC is stored as carbonate coasts within in the gravel fraction. We measured a high level of pedon-scale field variability (up to 220%) among the three faces of 1 m3 soil pits. Analytical error associated with the modified pressure calcimeter (0.001-0.014%), is considerably less than naturally occurring heterogeneities in SIC within the soil profile. This work highlights and quantifies two sources of uncertainty in studies of SIC needed to inform future research. First, in gravelly sites, the >2 mm portion of soils may store a large percentage of SIC. Second, SIC varies considerably at the pedon-scale, so studies attempting to quantify carbon storage over landscape scales need to consider this variability. This study creates a framework for understanding SIC in Reynolds Creek that may be applied to future work.."--Boise State University ScholarWorks.

Weathering Controls on Mechanisms of Carbon Storage in Grassland Soils

Weathering Controls on Mechanisms of Carbon Storage in Grassland Soils PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
On a sequence of soils developed under similar vegetation, temperature, and precipitation conditions, but with variations in mineralogical properties, we use organic carbon and 14C inventories to examine mineral protection of soil organic carbon. In these soils, 14C data indicate that the creation of slow-cycling carbon can be modeled as occurring through reaction of organic ligands with Al3+ and Fe3+ cations in the upper horizons, followed by sorption to amorphous inorganic Al compounds at depth. Only one of these processes, the chelation of Al3+ and Fe3+ by organic ligands, is linked to large carbon stocks. Organic ligands stabilized by this process traverse the soil column as dissolved organic carbon (both from surface horizons and root exudates). At our moist grassland site, this chelation and transport process is very strongly correlated with the storage and long-term stabilization of soil organic carbon. Our 14C results show that the mechanisms of organic carbon transport and storage at this site follow a classic model previously believed to only be significant in a single soil order (Spodosols), and closely related to the presence of forests. The presence of this process in the grassland Alfisol, Inceptisol, and Mollisol soils of this chronosequence suggests that this process is a more significant control on organic carbon storage than previously thought.

The Role of Soil Inorganic Carbon in Carbon Sequestration

The Role of Soil Inorganic Carbon in Carbon Sequestration PDF Author: Gil Eshel
Publisher:
ISBN:
Category :
Languages : en
Pages : 302

Book Description


Identifying Controls on Surface Carbon Dioxide Efflux in a Semi-arid Ecosystem

Identifying Controls on Surface Carbon Dioxide Efflux in a Semi-arid Ecosystem PDF Author: Katrina Elsie Ladd
Publisher:
ISBN:
Category : Carbon dioxide
Languages : en
Pages : 218

Book Description


Assessing Biotic and Abiotic Controls of Carbon Storage in Soil

Assessing Biotic and Abiotic Controls of Carbon Storage in Soil PDF Author: Avishesh Neupane
Publisher:
ISBN:
Category :
Languages : en
Pages : 167

Book Description
Understanding the mechanisms of soil carbon (C) formation and loss is essential for predicting the C storage capacity of soils under ongoing global change scenarios. Climatic variables, vegetation structure, microbial activity, soil mineralogy, and tissue C chemistry each have the potential to affect the fate of C in soils, and the interactions among these controls vary in different environments. Our mechanistic understanding of how these factors interact with each other to determine soil C storage is still rudimentary. This dissertation used a series of field and laboratory studies to assess the interacting roles of vegetation, soil mineralogy, microbial activity, C chemistry, and temperature in regulating the fate of C in soils. In the first experiment, we sought to understand how soil mineralogy, soil nutrient and C status, and C chemistry interact to determine warming effects on the fate of newly added soil C using a 13C isotopic tracing approach. By tracking the added 13C label in soil pools at 4 days and 255 days in tropical forest soils with differing weathering and mineralogical conditions, we found that initial microbial uptake of 13C and average carbon use efficiency (CUE) by microbes were strongly correlated with longer-term C retention in mineral soils. Overall, warming had a negative effect on 13C retention in soil in the youngest, least-weathered soil only, with no warming effect on moderately to strongly weathered soils. Thus, soil C stocks in less weathered soils, and with lower microbial CUE, may be most vulnerable to C loss with a warming climate. Our second study assessed the fate of newly added organic 13C-labeled compounds in soils of differing fertility along weathering gradients. Comparing additions of two low molecular weight compounds, 2.9x greater retention occurred for 13C-labeled glucose versus 13C-labeled glycine after two years, suggesting that glucose may be a better precursor for soil organic matter formation. Soil mineralogy and nutrient availability were not significant factors in 13C retention in soil. Soil spectra from 13C NMR revealed an increase in the proportion of alkyl C in glucose and glycine amended soil relative to control soils, and alkyl C are commonly associated with relatively stable organic C. Thus, our results indicate that microbial incorporation of labile organic compounds like glucose into biomass may be associated with greater C retention in stable soil components. Our third study estimated the long-term effect of grass cover loss on soil organic C (SOC) and total nitrogen (TN) storage, and the spatial heterogeneity of SOC and TN in two arid grasslands. The nine years of experimental grass removal resulted in soil deflation and 30% and 35% declines in SOC and TN respectively in 100% grass removal plots (TU100). Grass removal also led to soil deposition in downwind areas of the plot (TD100). Soil organic C and TN concentrations in the deposition plot (TD100) was variable, and likely depended on the structure of the vegetation community trapping wind-blown particulates. Geostatistical analysis showed that weaker and smaller fertile islands, compared to the control, developed in TD100 plots over nine years of aeolian transport. The outcomes of this dissertation will add to the current body of knowledge about mechanisms of soil C stabilization across environmental conditions and with warming.

Carbon Sequestration in Soils

Carbon Sequestration in Soils PDF Author: Norman J. Rosenberg
Publisher:
ISBN:
Category : Science
Languages : en
Pages : 220

Book Description
Carbon dioxide accumulation in the atmosphere as the result of fossil fuel emissions and land use change (especially tropical deforestation) threatens to cause global warming and climatic change. One means of reducing the increase in atmospheric carbon dioxide is through its capture by photosynthesis and storage (sequestration) in soil. The quantities of carbon that can be sequestered during the next century are enough to offset two or three decades' worth of carbon emissions at the current rate. The book deals with four issues that must be addressed before soil carbon sequestration programs can be implemented on a large scale: new science, monitoring and verification, the soil carbon sequestration/desertification linkage, and policy and implementation issues. Contents include - Science Needs and New Technology for Soil Carbon Sequestration - Monitoring and Verifying Soil Organic Carbon Sequestration - Desertification Control to Sequester C and Mitigate the Greenhouse Effect - Soil Carbon: Policy and Economics - Science Needs and New Technologies - Monitoring and Verifying - Desertification

Temporal Variability in the Concentration and Stable Carbon Isotope Composition of Dissolved Inorganic and Organic Carbon in Two Montana, USA Rivers

Temporal Variability in the Concentration and Stable Carbon Isotope Composition of Dissolved Inorganic and Organic Carbon in Two Montana, USA Rivers PDF Author: Stephen R. Parker
Publisher:
ISBN:
Category : Carbon
Languages : en
Pages :

Book Description


Landuse and Soil Organic Carbon Variability in the Old Woman Creek Watershed of North Central Ohio

Landuse and Soil Organic Carbon Variability in the Old Woman Creek Watershed of North Central Ohio PDF Author: Jeffrey T. Kroll
Publisher:
ISBN:
Category : Land use
Languages : en
Pages : 122

Book Description
This study investigated the variability of soil organic carbon within the Old Woman Creek watershed and the influence of landuse, soil texture, geomorphic surface and depth on SOC variability. Soil samples were collected at 0-30 cm and 30-60 cm depths in forest, pasture, conservation tillage and conventional tillage sites in both the Lake Plain and Till Plain. The Lake Plain had higher SOC than the Till Plain, and geomorphic surface had a greater affect at the 30-60cm depth than the 0-30cm depth. SOC was higher at the 0-30cm depth than the 30-60cm depth. Forest and pasture landuses had higher SOC than conservation and conventional tillage landuses. Conventional tillage had higher SOC than conservation tillage. Linear regression models and soil survey data were used to extrapolate SOC data to the watershed. Linear regression models could be useful estimators of SOC when used with site-specific data.

Carbon-water Cycling in the Critical Zone

Carbon-water Cycling in the Critical Zone PDF Author:
Publisher:
ISBN:
Category :
Languages : en
Pages : 6

Book Description
One of the largest knowledge gaps in environmental science is the ability to understand and predict how ecosystems will respond to future climate variability. The links between vegetation, hydrology, and climate that control carbon sequestration in plant biomass and soils remain poorly understood. Soil respiration is the second largest carbon flux of terrestrial ecosystems, yet there is no consensus on how respiration will change as water availability and temperature co-vary. To address this knowledge gap, we use the variation in soil development and topography across an elevation and climate gradient on the Front Range of Colorado to conduct a natural experiment that enables us to examine the co-evolution of soil carbon, vegetation, hydrology, and climate in an accessible field laboratory. The goal of this project is to further our ability to combine plant water availability, carbon flux and storage, and topographically driven hydrometrics into a watershed scale predictive model of carbon balance. We hypothesize: (i) landscape structure and hydrology are important controls on soil respiration as a result of spatial variability in both physical and biological drivers: (ii) variation in rates of soil respiration during the growing season is due to corresponding shifts in belowground carbon inputs from vegetation; and (iii) aboveground carbon storage (biomass) and species composition are directly correlated with soil moisture and therefore, can be directly related to subsurface drainage patterns.

Vegetation Controls on the Dynamics and Quality of Soil Organic Carbon in an Arid, Hyperthermic Ecosystem

Vegetation Controls on the Dynamics and Quality of Soil Organic Carbon in an Arid, Hyperthermic Ecosystem PDF Author: David Allen White II
Publisher:
ISBN:
Category :
Languages : en
Pages : 252

Book Description
Arid lands comprise vast regions of terrestrial land, highlighting the importance of understanding their role in the global carbon cycle. The objective of this study was to determine the effect of Prosopis velutina (mesquite), Larrea tridentata (creosote) and a combination of Bouteloua barbata , Bouteloua aristidoides , Aristida adscensionis , and some Cynodon dactylon (mixed grass) vegetation types on soil organic carbon (SOC) dynamics and quality in an arid, hyperthermic ecosystem of southern Arizona. This was accomplished by quantifying vegetation type control over: (i) local scale SOC stocks; (ii) soil aggregate stability; (iii) SOC turnover and microbial community composition; (iv) the distribution of SOC in physically defined fractions; and (v) the thermal nature and composition of SOC. The results from this study demonstrated significant variation in SOC dynamics and quality between vegetation with potential feedbacks to SOC sequestration of atmospheric CO2.