Conjugated Polymer Electrochromic and Light-emitting Devices PDF Download
Are you looking for read ebook online? Search for your book and save it on your Kindle device, PC, phones or tablets. Download Conjugated Polymer Electrochromic and Light-emitting Devices PDF full book. Access full book title Conjugated Polymer Electrochromic and Light-emitting Devices by Aubrey L. Dyer. Download full books in PDF and EPUB format.
Author: Aubrey L. Dyer Publisher: ISBN: Category : Languages : en Pages :
Book Description
ABSTRACT: Chemistry Conjugated conducting polymers are among some of the most versatile materials to emerge in the past 20 years. They have been researched for applications that range from photovoltaics, to light-emitting diodes, electrochromic windows, actuators, and field effect transistors. This work details the analytical characterization of [pi]-conjugated polymers to understand their redox and optical properties, along with the development of several new types of devices that employ these polymers as the active materials for both variable optical attenuators and as dual electrochromic/electroluminescent displays. Within this work, a phenomenon that we term unsymmetrical switching has been uncovered for the first time in reflective electrochromic cells. The unsymmetrical switching in these displays is explored and a model devised to illustrate that the presence of a conductive front propagating through the polymer film on electrochemical oxidation is the contributing cause for this observation. For these experiments, a variety of analytical techniques have been utilized to characterize the devices and materials contained therein and include electrochemistry, spectroelectrochemistry, and photometry.
Author: Aubrey L. Dyer Publisher: ISBN: Category : Languages : en Pages :
Book Description
ABSTRACT: Chemistry Conjugated conducting polymers are among some of the most versatile materials to emerge in the past 20 years. They have been researched for applications that range from photovoltaics, to light-emitting diodes, electrochromic windows, actuators, and field effect transistors. This work details the analytical characterization of [pi]-conjugated polymers to understand their redox and optical properties, along with the development of several new types of devices that employ these polymers as the active materials for both variable optical attenuators and as dual electrochromic/electroluminescent displays. Within this work, a phenomenon that we term unsymmetrical switching has been uncovered for the first time in reflective electrochromic cells. The unsymmetrical switching in these displays is explored and a model devised to illustrate that the presence of a conductive front propagating through the polymer film on electrochemical oxidation is the contributing cause for this observation. For these experiments, a variety of analytical techniques have been utilized to characterize the devices and materials contained therein and include electrochemistry, spectroelectrochemistry, and photometry.
Author: Inamuddin Publisher: John Wiley & Sons ISBN: 1119654602 Category : Technology & Engineering Languages : en Pages : 288
Book Description
Polymers for Light-Emitting Devices and Displays provides an in-depth overview of fabrication methods and unique properties of polymeric semiconductors, and their potential applications for LEDs including organic electronics, displays, and optoelectronics. Some of the chapter subjects include: • The newest polymeric materials and processes beyond the classical structure of PLED • Conjugated polymers and their application in the light-emitting diodes (OLEDs & PLEDs) as optoelectronic devices. • The novel work carried out on electrospun nanofibers used for LEDs. • The roles of diversified architectures, layers, components, and their structural modifications in determining efficiencies and parameters of PLEDs as high-performance devices. • Polymer liquid crystal devices (PLCs), their synthesis, and applications in various liquid crystal devices (LCs) and displays. • Reviews the state-of-art of materials and technologies to manufacture hybrid white light-emitting diodes based on inorganic light sources and organic wavelength converters.
Author: Janelle Leger Publisher: CRC Press ISBN: 9781138116504 Category : Languages : en Pages : 247
Book Description
The field of organic electronics promises exciting new technologies based on inexpensive and mechanically flexible electronic devices, and is now seeing the beginning of commercial success. On the sidelines of this increasingly well-established field are several emerging technologies with innovative mechanisms and functions that utilize the mixed ionic/electronic conducting character of conjugated organic materials. Iontronics: Ionic Carriers in Organic Electronic Materials and Devices explores the potential of these materials, which can endow electronic devices with unique functionalities. Fundamental science and applications With contributions from a community of experts, the book focuses on the use of ionic functions to define the principle of operation in polymer devices. It begins by reviewing the scientific understanding and important scientific discoveries in the electrochemistry of conjugated polymers. It examines the known effects of ion incorporation, including the theory and modulation of electrochemistry in polymer films, and it explores the coupling of electronic and ionic transport in polymer films. The authors also describe applications that use this technology, including polymer electrochromic devices, artificial muscles, light-emitting electrochemical cells, and biosensors, and they discuss the fundamental technological hurdles in these areas. The changes in materials properties and device characteristics due to ionic conductivity and electrochemical doping in electrically conductive organic materials, as well as the importance of these processes in a number of different and exciting technologies, point to a large untapped potential in the development of new applications and novel device architecture. This volume captures the state of the science in this burgeoning field.
Author: Huisheng Peng Publisher: Academic Press ISBN: 0128110929 Category : Technology & Engineering Languages : en Pages : 388
Book Description
Polymer Materials for Energy and Electronic Applications is among the first books to systematically describe the recent developments in polymer materials and their electronic applications. It covers the synthesis, structures, and properties of polymers, along with their composites. In addition, the book introduces, and describes, four main kinds of electronic devices based on polymers, including energy harvesting devices, energy storage devices, light-emitting devices, and electrically driving sensors. Stretchable and wearable electronics based on polymers are a particular focus and main achievement of the book that concludes with the future developments and challenges of electronic polymers and devices. Provides a basic understanding on the structure and morphology of polymers and their electronic properties and applications Highlights the current applications of conducting polymers on energy harvesting and storage Introduces the emerging flexible and stretchable electronic devices Adds a new family of fiber-shaped electronic devices
Author: Roger J. Mortimer Publisher: John Wiley & Sons ISBN: 3527336109 Category : Technology & Engineering Languages : en Pages : 668
Book Description
Electrochromic materials can change their properties under the influence of an electrical voltage or current. Different classes of materials show this behavior such as transition metal oxides, conjugated polymers, metal-coordinated complexes and organic molecules. As the color change is persistent, the electric field needs only to be applied to initiate the switching, allowing for applications such as low-energy consumption displays, light-adapting mirrors in the automobile industry and smart windows for which the amount of transmitted light and heat can be controlled. The first part of this book describes the different classes and processing techniques of electrochromic materials. The second part highlights nanostructured electrochromic materials and device fabrication, and the third part focuses on the applications such as smart windows, adaptive camouflage, biomimicry, wearable displays and fashion. The last part rounds off the book by device case studies and environmental impact issues.
Author: Seth C. Rasmussen Publisher: American Chemical Society ISBN: 0841299609 Category : Science Languages : en Pages : 198
Book Description
This digital primer serves as an excellent introduction to conjugated polymers, particularly in terms of their synthesis and design. Chapters one and two introduce common terminology and fundamental concepts. Chapter three covers known structure–function relationships that can be used to design conjugated polymers with the desired properties for specific applications, concluding with a discussion of the additive and sometimes conflicting aspects of these design elements. Chapters four, five, and six cover the various methods used to synthesize these materials, beginning with the oldest and most simple approaches, and increasing in synthetic complexity. Advanced undergraduates, graduate students, and faculty wishing to enter this field for the first time should find this primer beneficial. At the same time, however, we have pointed out various misconceptions still commonly found in the literature, which should be valuable to those already familiar with these materials.
Author: Tanmoy Dey Publisher: ISBN: Category : Electronic dissertations Languages : en Pages :
Book Description
Electrochromism is a process by which a material can change its electronic-optical properties upon charge injection/removal. Conjugated polymers are an interesting class of electrochromic materials because of their color tunability, high optical contrasts, fast switching speeds, and processability. Poly(3,4-propylenedioxy)thiophenes (PProDOT) are a substantial subclass of materials in conjugated polymer electrochromics due to their high optical contract between the bleached and colored states. Common derivatives of this molecule are typically made at the beta position with respect to oxygen on the seven membered ring. PProDOTs with methyl and benzyl substituents (beta position with respect to oxygen) are two of the more successful due to their high contrast. We have found that there is a much more substantial effect when PProDOT is derivatized in the positions alpha to the oxygen. For example, two t-butyl groups with each placed alpha to the oxygen in PProDOT incurs a 200 nm shift in the lambda max (365 nm) compared to having two methyl groups with each placed alpha to the oxygen. The dimethyl derivative is blue in color whereas the di-t-butyl, dihexyl, diisopropyl is showing yellow, orange and red color respectively. The polymer of this new derivative, P13ProDOT-TB2 and P13ProDOT-Hex 2 is organic-soluble and can be processed by a variety of solution methods, including spray coating. Furthermore we have also studied some selenium based polymer for electrochromic application. Poly(3,4-propylenedioxy)selenophenes (PProDOS) is showing better optical contrast, stability and faster switching speed as compared to their sulfur analogs. Low band gap conducting polymers (CPs) have relatively low absorption in the visible region, in their conducting states, making them promising candidates for optically transparent electrode, hole-injection layer for light-emitting diodes and suitable donor material for Photovoltaics. The monomer, Seleno[3,2- c]thiophene and Seleno[3,4-b]thiophene, were electrochemically and polymerized to produce new low band gap conducting polymer, poly(Seleno[3,2- c]thiophene) (PS32cT) and Poly(Seleno[3,4-b]thiophene) (PS34bT), having a low band gap of 1.03 eV and 1.50 eV respectively. Besides from the suitable energy gap, they also offer a good match of the absolute energy levels with the other materials in the photovoltaic device. The HOMO of the low band gap polymers agree with the work function of ITO and LUMO matches with the acceptor level of PCBM. This overlap is very important to the function of photovoltaic devices. In a different approach we describe a new alternative route for the synthesis of thieno[3,4-b]thiophene, alkyl derivatives thereof, seleno[3,4- b]thiophene, and thieno[3,4-b]furan made from inexpensive starting materials, such as thiophene-2-carboxylic acid and furan-2-carboxylic acid. Such fused heterocycles are of great interest for low band gap organic semiconductors and applications including OLEDs, organic photovoltaic cells, and electrochromic applications.
Author: Terje A. Skotheim Publisher: CRC Press ISBN: 9781420043600 Category : Technology & Engineering Languages : en Pages : 656
Book Description
Many significant fundamental concepts and practical applications have developed since the publication of the best-selling second edition of the Handbook of Conducting Polymers. Now divided into two books, the third edition continues to retain the excellent expertise of the editors and world-renowned contributors while providing superior coverage of the recent advances in polymer processing and applications, particularly in conductivity, nonlinear optics, and light emission. Conjugated Polymers: Processing and Applications, the second of two volumes, picks up where the first volume ended. It concentrates on the numerous processing methods for conducting polymers and their integration into various devices and applications. The book first examines coating, printing, and spinning methods for complex patterned films and fibers. It then shows how conducting and semiconducting polymers are applied in many devices, such as light-emitting displays, solar cells, field effect transistors, electrochromic panels, charge storage devices, biosensors, and actuators. Following the essential scientific information found in the first installment, this book explores the ways in which polymers are useful in industrial and commercial applications. These application developments have already led to marketable products.
Author: Terje A. Skotheim Publisher: CRC Press ISBN: 1420043617 Category : Technology & Engineering Languages : en Pages : 664
Book Description
Many significant fundamental concepts and practical applications have developed since the publication of the best-selling second edition of the Handbook of Conducting Polymers. Now divided into two books, the third edition continues to retain the excellent expertise of the editors and world-renowned contributors while providing superior coverage of
Author: Aubrey L. Dyer
Author: Aubrey L. Dyer
Author: Inamuddin
Author: Janelle Leger
Author: Huisheng Peng
Author: Roger J. Mortimer
Author: Seth C. Rasmussen
Author: Tanmoy Dey
Author: Terje A. Skotheim
Author: Terje A. Skotheim
Author: Sze C. Yang