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CO2 Conversion and Utilization

CO2 Conversion and Utilization PDF Author: Chunshan Song
Publisher: ACS Symposium
ISBN: 9780841237476
Category : Science
Languages : en
Pages : 0

Book Description
This book focuses on the chemistry and processes for conversion and utilization of carbon dioxide. Topics include CO 2 utilization, its conversion to industrial chemicals and fuels, its coversion via synthesis gas, and new catalysts and chemical processes for conversion.

CO2 Conversion and Utilization

CO2 Conversion and Utilization PDF Author: Chunshan Song
Publisher: ACS Symposium
ISBN: 9780841237476
Category : Science
Languages : en
Pages : 0

Book Description
This book focuses on the chemistry and processes for conversion and utilization of carbon dioxide. Topics include CO 2 utilization, its conversion to industrial chemicals and fuels, its coversion via synthesis gas, and new catalysts and chemical processes for conversion.

Solar Fuel Generation

Solar Fuel Generation PDF Author: Yatendra S. Chaudhary
Publisher: CRC Press
ISBN: 131535344X
Category : Science
Languages : en
Pages : 248

Book Description
As the search for renewable sources of energy grows more urgent, more and more attention is focusing on the blueprint offered by biological photosynthesis for translating the energy of our Sun into energy rich molecules like H2 and carbohydrates, commonly known as "solar fuels." These solar fuels have enormous potential to store high densities of energy in the form of chemical bonds as well as being transportable. This book offers a complete overview of the promising approaches to solar fuel generation, including the direct pathways of solar H2 generation and CO2 photocatalytic reduction. Solar Fuel Generation is an invaluable tool for graduate students and researchers (especially chemists, physicists, and material scientists) working in this field.

CO2 Photocatalytic Reduction to Fuels

CO2 Photocatalytic Reduction to Fuels PDF Author: Alejandro Castañeda Flores
Publisher:
ISBN:
Category : Carbon dioxide mitigation
Languages : en
Pages : 72

Book Description
A new photocatalytic material was synthesized to investigate its performance for the photoreduction of carbon dioxide (CO2) in the presence of water vapor (H2O) to valuable products such as carbon monoxide (CO) and methane (CH4). The performance was studied using a gas chromatograph (GC) with a flame ionization detector (FID) and a thermal conductivity detector (TCD). The new photocatalytic material was an ionic liquid functionalized reduced graphite oxide (IL-RGO (high conductive surface))-TiO2 (photocatalyst) nanocomposite. Brunauer-Emmett-Teller (BET), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and UV-vis absorption spectroscopy techniques were employed to characterize the new catalyst. In the series of experiments performed, the nanocomposite material was confined in a UV-quartz batch reactor, exposed to CO2 and H2O and illuminated by UV light. The primary product formed was CO with a maximum production ranging from 0.18-1.02 mol(gcatalyst-hour)-1 for TiO2 and 0.41-1.41 mol(gcatalyst-hour)-1 for IL-RGO-TiO2. A trace amount of CH4 was also formed with its maximum ranging from 0.009-0.01 mol(gcatalyst-hour)-1 for TiO2 and 0.01-0.04 mol(gcatalyst-hour)-1 for IL-RGO-TiO2. A series of background experiments were conducted and results showed that; (a) the use of a ionic liquid functionalized reduced graphite oxide -TiO2 produced more products as compared to commercial TiO2, (b) the addition of methanol as a hole scavenger boosted the production of CO but not CH4, (c) a higher and lower reduction time of IL-RGO as compared to the usual 24 hours of reduction presented basically the same production of CO and CH4, (d) the positive effect of having an ionic liquid was demonstrated by the double production of CO obtained for IL-RGO-TiO2 as compared to RGO-TiO2 and (e) a change in the amount of IL-RGO in the IL-RGO-TiO2 represented a small difference in the CO production but not in the CH4 production. This work ultimately demonstrated the huge potential of the utility of a UV-responsive ionic liquid functionalized reduced graphite oxide-TiO2 nano-composite for the reduction of CO2 in the presence of H2O for the production of fuels.

Solar-to-Chemical Conversion

Solar-to-Chemical Conversion PDF Author: Hongqi Sun
Publisher: John Wiley & Sons
ISBN: 3527825088
Category : Science
Languages : en
Pages : 480

Book Description
This comprehensive book systematically covers the fundamentals in solar energy conversion to chemicals, either fuels or chemical products. It includes natural photosynthesis with emphasis on artificial processes for solar energy conversion and utilization. The chemical processes of solar energy conversion via homogeneous and/or heterogeneous photocatalysis has been described with the mechanistic insights. It also consists of reaction systems toward a variety of applications, such as water splitting for hydrogen or oxygen evolution, photocatalytic CO2 reduction to fuels, and light driven N2 fixation, etc. This unique book offers the readers a broad view of solar energy utilization based on chemical processes and their perspectives for future sustainability.

Photo- and Electro-Catalytic Processes

Photo- and Electro-Catalytic Processes PDF Author: Jianmin Ma
Publisher: John Wiley & Sons
ISBN: 352734859X
Category : Technology & Engineering
Languages : en
Pages : 596

Book Description
Explore green catalytic reactions with this reference from a renowned leader in the field Green reactions—like photo-, photoelectro-, and electro-catalytic reactions—offer viable technologies to solve difficult problems without significant damage to the environment. In particular, some gas-involved reactions are especially useful in the creation of liquid fuels and cost-effective products. In Photo- and Electro-Catalytic Processes: Water Splitting, N2 Fixing, CO2 Reduction, award-winning researcher Jianmin Ma delivers a comprehensive overview of photo-, electro-, and photoelectron-catalysts in a variety of processes, including O2 reduction, CO2 reduction, N2 reduction, H2 production, water oxidation, oxygen evolution, and hydrogen evolution. The book offers detailed information on the underlying mechanisms, costs, and synthetic methods of catalysts. Filled with authoritative and critical information on green catalytic processes that promise to answer many of our most pressing energy and environmental questions, this book also includes: Thorough introductions to electrocatalytic oxygen reduction and evolution reactions, as well as electrocatalytic hydrogen evolution reactions Comprehensive explorations of electrocatalytic water splitting, CO2 reduction, and N2 reduction Practical discussions of photoelectrocatalytic H2 production, water splitting, and CO2 reduction In-depth examinations of photoelectrochemical oxygen evolution and nitrogen reduction Perfect for catalytic chemists and photochemists, Photo- and Electro-Catalytic Processes: Water Splitting, N2 Fixing, CO2 Reduction also belongs in the libraries of materials scientists and inorganic chemists seeking a one-stop resource on the novel aspects of photo-, electro-, and photoelectro-catalytic reactions.

New and Future Developments in Catalysis

New and Future Developments in Catalysis PDF Author: Steven L Suib
Publisher: Newnes
ISBN: 0444538836
Category : Technology & Engineering
Languages : en
Pages : 659

Book Description
New and Future Developments in Catalysis is a package of books that compile the latest ideas concerning alternate and renewable energy sources and the role that catalysis plays in converting new renewable feedstock into biofuels and biochemicals. Both homogeneous and heterogeneous catalysts and catalytic processes will be discussed in a unified and comprehensive approach. There will be extensive cross-referencing within all volumes.This volume presents a complete picture of all carbon dioxide (CO2) sources, outlines the environmental concerns regarding CO2, and critically reviews all current CO2 activation processes. Furthermore, the volume discusses all future developments and gives a critical economic analysis of the various processes. - Offers in-depth coverage of all catalytic topics of current interest and outlines future challenges and research areas - A clear and visual description of all parameters and conditions, enabling the reader to draw conclusions for a particular case - Outlines the catalytic processes applicable to energy generation and design of green processes

Visible-Light-Active Photocatalysis

Visible-Light-Active Photocatalysis PDF Author: Srabanti Ghosh
Publisher: John Wiley & Sons
ISBN: 3527342931
Category : Science
Languages : en
Pages : 624

Book Description
A comprehensive and timely overview of this important and hot topic, with special emphasis placed on environmental applications and the potential for solar light harvesting. Following introductory chapters on environmental photocatalysis, water splitting, and applications in synthetic chemistry, further chapters focus on the synthesis and design of photocatalysts, solar energy conversion, and such environmental aspects as the removal of water pollutants, photocatalytic conversion of CO2. Besides metal oxide-based photocatalysts, the authors cover other relevant material classes including carbon-based nanomaterials and novel hybrid materials. Chapters on mechanistic aspects, computational modeling of photocatalysis and Challenges and perspectives of solar reactor design for industrial applications complete this unique survey of the subject. With its in-depth discussions ranging from a comprehensive understanding to the engineering of materials and applied devices, this is an invaluable resource for a range of disciplines.

Green Carbon Dioxide

Green Carbon Dioxide PDF Author: Gabriele Centi
Publisher: John Wiley & Sons
ISBN: 1118831942
Category : Technology & Engineering
Languages : en
Pages : 284

Book Description
PROMISING NEW APPROACHES TO RECYCLE CARBON DIOXIDE AND REDUCE EMISSIONS With this book as their guide, readers will learn a variety of new approaches and methods to recycle and reuse carbon dioxide (CO2) in order to produce green fuels and chemicals and, at the same time, minimize CO2 emissions. The authors demonstrate how to convert CO2 into a broad range of essential products by using alternative green energy sources, such as solar, wind, and hydro-power as well as sustainable energy sources. Readers will discover that CO2 can be a driving force for the sustainable future of both the chemical industry and the energy and fuels industry. Green Carbon Dioxide features a team of expert authors, offering perspectives on the latest breakthroughs in CO2 recycling from Asia, Europe, and North America. The book begins with an introduction to the production of CO2-based fuels and chemicals. Next, it covers such topics as: Transformation of CO2 to useable products through free-radical-induced reactions Hydrogenation of CO2 to liquid fuels Direct synthesis of organic carbonates from CO2 and alcohols using heterogeneous oxide catalysts Electrocatalytic reduction of CO2 in methanol medium Fuel production from photocatalytic reduction of CO2 with water using TiO2-based nanocomposites Use of CO2 in enhanced oil recovery and carbon capture and sequestration More than 1,000 references enable readers to explore individual topics in greater depth. Green Carbon Dioxide offers engineers, chemists, and managers in the chemical and energy and fuel industries a remarkable new perspective, demonstrating how CO2 can play a significant role in the development of a sustainable Earth.

Multifunctional Nanocomposites for Energy and Environmental Applications

Multifunctional Nanocomposites for Energy and Environmental Applications PDF Author: Zhanhu Guo
Publisher: John Wiley & Sons
ISBN: 3527342478
Category : Science
Languages : de
Pages : 693

Book Description
Dieses klar strukturierte Fachbuch legt den Schwerpunkt auf praktische Anwendungen von Nanokompositen und Nanotechnologien im Rahmen einer nachhaltigen Entwicklung. Es zeigt, wie Nanokomposite zur Lösung von Energie- und Umweltproblemen beitragen können, bietet zusätzlich einen breiten Überblick über Anwendungen im Energiebereich und behandelt eine einzigartige Auswahl an Umweltthemen. Der erste Teil beschäftigt sich mit Anwendungen wie Lithium-Ionen-Batterien, Solarzellen, Katalyse, Gewinnung von Wärme und Energie aus Abfällen mithilfe der Thermoelektrizität und Wasserspaltung. Der zweite Teil beleuchtet in einzigartiger Weise ökologische Themen, darunter Atommüllmanagement sowie die Abscheidung und Speicherung von Kohlendioxid. Dieses Fachbuch vermittelt auf erfolgreiche Weise Grundlagenwissen für Einsteiger als auch die neuesten Erkenntnisse für erfahrene Wissenschaftler, Ingenieure und Forscher aus der Industrie.

Green Photocatalytic Semiconductors

Green Photocatalytic Semiconductors PDF Author: Seema Garg
Publisher: Springer Nature
ISBN: 303077371X
Category : Science
Languages : en
Pages : 855

Book Description
This book comprises a detailed overview on the role of photocatalysts for environmental remediation, hydrogen production and carbon dioxide reduction. Effective ways to enhance the photocatalytic activity of the material via doping, hybrid material, laser light and nanocomposites have been discussed in this book. The book also further elaborates the role of metal nanoparticles, rare earth doping, sensitizers, surface oxygen vacancy, interface engineering and band gap engineering for enhancing the photocatalytic activity. An approach to recover the photocatalytic material via immobilization is also presented. This book brings to light much of the recent research in the development of such semiconductor photocatalytic systems. The book will thus be of relevance to researchers in the field of: material science, environmental science & technology, photocatalytic applications, newer methods of energy generation & conversion and industrial applications.