Catalytic Oxidation of S(IV) on Activated Carbon in Aqueous Suspension PDF Download

Author: Richard Brodzinsky
Publisher:
ISBN:
Category : Air
Languages : en
Pages : 78

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Category :
Languages : en
Pages :

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Activated carbon and combustion produced soot particles have been studied for their catalytic effect on the oxidation of aqueous sulfur(IV) species. Detailed kinetic studies of the reaction were performed on three different activated carbons and on a soot collected in a highway tunnel. Combustion produced soots were tested for their catalytic behavior and found to be similar to the activated carbons. The reaction rate was found to be linearly dependent on the concentration of carbon particles in the solution. The rate was found to follow a Langmuir adsorption isotherm for its dependence on oxygen and the product of two adsorption isotherms for S(IV). The reaction is independent of the pH of the solution when the pH is below 7.6. The reaction does not occur when the pH is above 7.6. The three aqueous S(IV) species are catalyzed in their oxidation by the carbon particles in a similar manner. Activation energies for the reactions on the different carbons are all about 8.5 kcal/mole. A possible four-step reaction mechanism is proposed. It consists of the adsorption of a dissolved oxygen molecule onto the carbon surface, followed by the adsorption of two S(IV) molecules or ions. These are oxidized on the surface to sulfate, which desorbs from the surface, regenerating the catalytically active site.

Author:
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ISBN:
Category : Medicine
Languages : en
Pages : 1620

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Vols. for 1963- include as pt. 2 of the Jan. issue: Medical subject headings.

Author: Takahiko Akiyama
Publisher: John Wiley & Sons
ISBN: 1119736412
Category : Science
Languages : en
Pages : 798

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Catalytic Asymmetric Synthesis Seminal text presenting detailed accounts of the most important catalytic asymmetric reactions known today This book covers the preparation of enantiomerically pure or enriched chemical compounds by use of chiral catalyst molecules. While reviewing the most important catalytic methods for asymmetric organic synthesis, this book highlights the most important and recent developments in catalytic asymmetric synthesis. Edited by two well-qualified experts, sample topics covered in the work include: Metal catalysis, organocatalysis, photoredox catalysis, enzyme catalysis C–H bond functionalization reactions Carbon–carbon bond formation reactions, carbon–halogen bond formation reactions, hydrogenations, polymerizations, flow reactions Axially chiral compounds Retaining the best of its predecessors but now thoroughly up to date with the important and recent developments in catalytic asymmetric synthesis, the 4th edition of Catalytic Asymmetric Synthesis serves as an excellent desktop reference and text for researchers and students, from upper-level undergraduates all the way to experienced professionals in industry or academia.

Author: P.A. Grieco
Publisher: Springer Science & Business Media
ISBN: 940114950X
Category : Science
Languages : en
Pages : 321

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The use of water as a medium for promoting organic reactions has been rather neglected in the development of organic synthesis, despite the fact that it is the solvent in which almost all biochemical processes take place. Chemists have only recently started to appreciate the enormous potential water has to offer in the development of new synthetic reactions and strategies, where it can offer benefits in both unique chemistry and reduced environmental impact. In this new book, the editor, well known for his contribution to the development of water as a useful medium in synthetic organic chemistry, has assembled an international team of authors, themselves at the forefront of research into the use of the unique properties of water carrying out organic transformations, to provide a timely and concise overview of current research. By focusing on the practical use of water in synthetic organic chemistry, and with the concern for the use of solvents in organic chemistry, professional chemists, particularly those involved in industrial research and development, will find this book an essential guide to the current state of the art, and a useful starting point in their own research. Academic chemists, including postgraduate and advanced undergraduate students, will find this book an invaluable guide to this exciting and important area of chemistry.

Author: Mei Zhang
Publisher: Springer
ISBN: 3319228617
Category : Technology & Engineering
Languages : en
Pages : 576

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This book covers a wide range of topics relating to carbon nanomaterials, from synthesis and functionalization to applications in advanced biomedical devices and systems. As they possess unique and attractive chemical, physical, optical, and even magnetic properties for various applications, considerable effort has been made to employ carbon nanomaterials (e.g., fullerenes, carbon nanotubes, graphene, nanodiamond) as new materials for the development of novel biomedical tools, such as diagnostic sensors, imaging agents, and drug/gene delivery systems for both diagnostics and clinical treatment. Tremendous progress has been made and the scattered literature continues to grow rapidly. With chapters by world-renowned experts providing an overview of the state of the science as well as an understanding of the challenges that lie ahead, Carbon Nanomaterials for Biomedical Applications is essential reading not only for experienced scientists and engineers in biomedical and nanomaterials areas, but also for graduate students and advanced undergraduates in materials science and engineering, chemistry, and biology.

Author: Srabanti Ghosh
Publisher: CRC Press
ISBN: 1000485323
Category : Technology & Engineering
Languages : en
Pages : 488

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Offering a comprehensive view of water-treatment technologies, Nanomaterials for Water Treatment and Remediation explores recent developments in the use of advanced nanomaterials (ANMs) for water treatment and remediation. In-depth reaction mechanisms in water-treatment technologies, including adsorption, catalysis, and membrane filtration for water purification using ANMs, are discussed in detail. The book includes an investigation of the fabrication processes of nanostructured materials and the fundamental aspects of surfaces at the nanoscale. The book also covers the removal of water-borne pathogens and microbes through a photochemical approach. FEATURES Explains various chemical treatments for the removal and separation of hazardous dyes, organic pollutants, pharmaceuticals, and heavy metals from aqueous solutions, including adsorption, advanced oxidation process, and photocatalysis Discusses the rational design of nanoporous materials with a tunable pore structure and fabrication of nanomaterials by surface chemistry engineering Covers the role of nanomaterials-assisted oxidation and reduction processes, design of nano-assisted membrane-based separation, and multifunctional nanomaterials and nanodevices for water treatment Provides an understanding of the structure–activity relationship and stability of ANMs under critical experimental conditions Identifies potential challenges in the application of multifunctional ANMs for future research Nanomaterials for Water Treatment and Remediation is aimed at researchers and industry professionals in chemical, materials, and environmental engineering as well as related fields interested in the application of advanced materials to water treatment and remediation.

Author: Janez Košmrlj
Publisher: Springer
ISBN: 3642294294
Category : Science
Languages : en
Pages : 245

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B. R. Buckley and H. Heaney: Mechanistic Investigations of Copper(I)- Catalyzed Alkyne–Azide Cycloaddition Reactions.- J. D. Crowley and D. A. McMorran: “Click-Triazole” Coordination Chemistry: Exploiting 1,4-Disubstituted-1,2,3-Triazoles as Ligands.- S. Lee and A. H. Flood: Binding Anions in Rigid and Reconfigurable Triazole Receptors.- M. Watkinson: Click Triazoles as Chemosensors.- H.-F. Chow, C.-M. Lo and Y. Chen: Triazole-Based Polymer Gels.- T. Zheng, S. H. Rouhanifard, A. S. Jalloh, P. Wu: Click Triazoles for Bioconjugation.- S. Mignani, Y. Zhou, T. Lecourt and L. Micouin: Recent Developments in the Synthesis 1,4,5-Trisubstituted Triazoles.

Author: Suresh C. Ameta
Publisher: Academic Press
ISBN: 0128105259
Category : Science
Languages : en
Pages : 430

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Advanced Oxidation Processes for Waste Water Treatment: Emerging Green Chemical Technology is a complete resource covering the fundamentals and applications of all Advanced Oxidation Processes (AOPs). This book presents the most up-to-date research on AOPs and makes the argument that AOPs offer an eco-friendly method of wastewater treatment. In addition to an overview of the fundamentals and applications, it details the reactive species involved, along with sections on reactor designs, thus helping readers understand and implement these methods. Presents in-depth coverage of all types of Advanced Oxidation Processes, including Super Critical Water Oxidation, Photo-Fenton and Like Processes Includes a fundamental review, applications, reactive species and reactor designs Reviews applications across waste types, including industrial waste, domestic and municipal sewage, and hospital wastes

Author: National Research Council
Publisher: National Academies Press
ISBN: 9780309052290
Category : Science
Languages : en
Pages : 450

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This volume updates and combines two National Academy Press bestsellers--Prudent Practices for Handling Hazardous Chemicals in Laboratories and Prudent Practices for Disposal of Chemicals from Laboratories--which have served for more than a decade as leading sources of chemical safety guidelines for the laboratory. Developed by experts from academia and industry, with specialties in such areas as chemical sciences, pollution prevention, and laboratory safety, Prudent Practices for Safety in Laboratories provides step-by-step planning procedures for handling, storage, and disposal of chemicals. The volume explores the current culture of laboratory safety and provides an updated guide to federal regulations. Organized around a recommended workflow protocol for experiments, the book offers prudent practices designed to promote safety and it includes practical information on assessing hazards, managing chemicals, disposing of wastes, and more. Prudent Practices for Safety in Laboratories is essential reading for people working with laboratory chemicals: research chemists, technicians, safety officers, chemistry educators, and students.