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Author: Publisher: ISBN: Category : Languages : en Pages : 8
Book Description
This program is directed at furthering the development of a metal- membrane-based process for economically producing pure hydrogen from the raw gasifier stream. A related program is directed at developing a metal-membrane-based process for cleanly and efficiently removing hydrogen sulfide from the hot gas stream. Both of these processes would be accomplished at 500°C to 800°C and are based on a novel hydrogen-permeable composite-metal membrane. Specific program objectives include (1) design, fabrication, and demonstration of pre-prototype membrane modules; (2) improving the membrane composition to increase the hydrogen flux; (3) evaluating membrane lifetime; and (4) conducting engineering and economic analyses of the processes.
Author: Publisher: ISBN: Category : Languages : en Pages : 8
Book Description
This program is directed at furthering the development of a metal- membrane-based process for economically producing pure hydrogen from the raw gasifier stream. A related program is directed at developing a metal-membrane-based process for cleanly and efficiently removing hydrogen sulfide from the hot gas stream. Both of these processes would be accomplished at 500°C to 800°C and are based on a novel hydrogen-permeable composite-metal membrane. Specific program objectives include (1) design, fabrication, and demonstration of pre-prototype membrane modules; (2) improving the membrane composition to increase the hydrogen flux; (3) evaluating membrane lifetime; and (4) conducting engineering and economic analyses of the processes.
Author: Publisher: ISBN: Category : Languages : en Pages : 7
Book Description
This program is directed toward the development of a metal-membrane-based process for the economical production of hydrogen at elevated temperature by the reaction of carbon monoxide with steam--i.e., the water-gas shift (WGS) reaction. Key to achieving this objective is the development of an inexpensive and durable metal-membrane module. The specific program objectives include the following: design, fabrication, and demonstration of prototype membrane modules; improving the membrane composition to increase the hydrogen flux; demonstrating that membrane lifetime ≥2 years is likely to be achieved; and conducting engineering and economic analyses of the process. Results to date are given and discussed.
Author: Publisher: ISBN: Category : Languages : en Pages : 71
Book Description
Commercial carbon composite microfiltration membranes may be modified for gas separation applications by providing a gas separation layer with pores in the 1- to 10-nm range. Several organic polymeric precursors and techniques for depositing a suitable layer were investigated in this project. The in situ polymerization technique was found to be the most promising, and pure component permeation tests with membrane samples prepared with this technique indicated Knudsen diffusion behavior. The gas separation factors obtained by mixed-gas permeation tests were found to depend strongly on gas temperature and pressure indicating significant viscous flow at high-pressure conditions. The modified membranes were used to carry out simultaneous water gas shift reaction and product hydrogen separation. These tests indicated increasing CO conversions with increasing hydrogen separation. A simple process model was developed to simulate a catalytic membrane reactor. A number of simulations were carried out to identify operating conditions leading to product hydrogen concentrations over 90 percent. (VC).
Author: Panagiotis Smirniotis Publisher: Elsevier ISBN: 0444633537 Category : Technology & Engineering Languages : en Pages : 280
Book Description
Water Gas Shift Reaction: Research Developments and Applications outlines the importance of hydrogen as a future fuel, along with the various hydrogen production methods. The book explains the development of catalysts for Water Gas Shift (WGS) reaction at different temperatures and steam/CO ratios, and also discussing the effect of different dopants on the WGS activity of iron oxide and the promotion and inhibition roles of the dopants on the WGS activity of iron oxide are explained. In addition, the book describes extensive characterization of modified ferrite catalysts, especially with Mossbauer spectroscopy and its advantage in understanding properties of metal doped ferrite catalysts, the exact dopant location, and its effect on electron hopping capability and WGS activity of Fe redox couple. - Outlines the importance of the Water Gas Shift Reaction and its application for hydrogen production - Provides detailed information on potential catalysts, their development, and their pros and cons, giving the reader insights on how modified ferrite catalysts work at different temperatures and different steam to CO ratios - Reviews hydrogen technology, its current importance, and production methods - Presents a clear presentation of the topics with many graphics and tables - Offers basic and advanced knowledge of catalysts characterization instrumental techniques
Author: Marcello De Falco Publisher: Springer Science & Business Media ISBN: 0857291513 Category : Technology & Engineering Languages : en Pages : 244
Book Description
Membrane Reactors for Hydrogen Production Processes deals with technological and economic aspects of hydrogen selective membranes application in hydrogen production chemical processes. Membrane Reactors for Hydrogen Production Processes starts with an overview of membrane integration in the chemical reaction environment, formulating the thermodynamics and kinetics of membrane reactors and assessing the performance of different process architectures. Then, the state of the art of hydrogen selective membranes, membrane manufacturing processes and the mathematical modeling of membrane reactors are discussed. A review of the most useful applications from an industrial point of view is given. These applications include: natural gas steam reforming, autothermal reforming, water gas shift reaction, decomposition of hydrogen sulphide, and alkanes dehydrogenation. The final part is dedicated to the description of a pilot plant where the novel configuration was implemented at a semi-industrial scale. Plant engineers, researchers and postgraduate students will find Membrane Reactors for Hydrogen Production Processes a comprehensive guide to the state of the art of membrane reactor technology.
Author: Zili Wu Publisher: Academic Press ISBN: 0128013400 Category : Technology & Engineering Languages : en Pages : 393
Book Description
Catalysis by Materials with Well-Defined Structures examines the latest developments in the use of model systems in fundamental catalytic science. A team of prominent experts provides authoritative, first-hand information, helping readers better understand heterogeneous catalysis by utilizing model catalysts based on uniformly nanostructured materials. The text addresses topics and issues related to material synthesis, characterization, catalytic reactions, surface chemistry, mechanism, and theoretical modeling, and features a comprehensive review of recent advances in catalytic studies on nanomaterials with well-defined structures, including nanoshaped metals and metal oxides, nanoclusters, and single sites in the areas of heterogeneous thermal catalysis, photocatalysis, and electrocatalysis. Users will find this book to be an invaluable, authoritative source of information for both the surface scientist and the catalysis practitioner - Outlines the importance of nanomaterials and their potential as catalysts - Provides detailed information on synthesis and characterization of nanomaterials with well-defined structures, relating surface activity to catalytic activity - Details how to establish the structure-catalysis relationship and how to reveal the surface chemistry and surface structure of catalysts - Offers examples on various in situ characterization instrumental techniques - Includes in-depth theoretical modeling utilizing advanced Density Functional Theory (DFT) methods
Author: Matthias Beller Publisher: Springer Science & Business Media ISBN: 354033002X Category : Science Languages : en Pages : 289
Book Description
Carbonylation reactions are of major importance in both organic and industrial chemistry. Due to the availability, price and reactivity pattern, carbon monoxide is becoming a more and more important building block for fine and bulk chemicals. The major reaction types of carbon monoxide are comprehensively discussed by leading experts from academia and industry. The authors highlight important carbonylation reactions such as hydroformylation, alkoxy-carbonylations, co/olefin-copolymerization, Pauson-Khand reactions and others. They illustrate applications in organic synthesis and give industrial examples. This volume is designed to provide graduate students and researchers with essential information on the use of carbon monoxide in organic synthesis. Therefore, the reader will get a balanced view of this developing and complex subject.
Author: José G. Sanchez Marcano Publisher: Wiley-VCH ISBN: 9783527323623 Category : Technology & Engineering Languages : en Pages : 0
Book Description
Through and Complete Overview of the Entire Field of Catalytic Membrane Reactors Catalysis in membrane reactors is the subject of much research. During the past three decades, this technical concept has attracted substantial worldwide attention and process development efforts. Catalytic Membranes and Membrane Reactors covers this fascinating field and presents the key concepts and innovative ideas to the reader. It is based on a well-balanced multidisciplinary approach to appeal to a wide audience of readers. Sample topics discussed within the work include: Basic principles of membrane reactors The membrane reactor concept in a practical sense The multidisciplinary aspects of catalytic membranes and membrane reactors Emerging technologies and the latest research advances in the field This book serves as a reference for understanding and applying the membrane reactor concept to research or production. Chemical engineers, process engineers, and professionals in the chemical and biotechnological industries will find value in it.
Author: Sang-Eon Park Publisher: Elsevier ISBN: 0080472176 Category : Technology & Engineering Languages : en Pages : 626
Book Description
Addressing global environmental problems, such as global warming is essential to global sustainability. Continued research leads to advancement in standard methods and produces new data. Carbon Dioxide Utilization for Global Sustainability: Proceedings of the 7th ICCDU (International Conference on Carbon Dioxide Utilization) reflects the most recent research results, as well as stimulating scientific discussions with new challenges in advancing the development of carbon dioxide utilization. Drawing on a wealth of information, this well structured book will benefit students, researchers and consultants looking to catch up on current developments in environmental and chemical engineering.* Provides comprehensive data on CO2 utilisation* Contains up-to-date information, including recent research trends* Is written for students, researchers and consultants in environmental and chemical engineering
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Author: Panagiotis Smirniotis
Author: Marcello De Falco
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Author: Zili Wu
Author: Matthias Beller
Author: José G. Sanchez Marcano
Author: Sang-Eon Park