Calculation of the Thermodynamic Properties of Fuel-vapor Species from Spectroscopic Data PDF Download
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Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
Measured spectroscopic data, estimated molecular parameters, and a densty-of-states model for electronic structure have been used to calculate thermodynamic functions for gaseous ThO, ThO2, UO, UO2, UO3, PuO, and PuO2. Various methods for estimating parameters have been considered and numerically evaluated. The sensitivity of the calculated thermodynamic functions to molecular parameters has been examined quantitatively. New values of the standard enthalpies of formation at 298.15°K have been derived from the best available .delta. G°/sub f/ equations and the calculated thermodynamic functions. Estimates of the uncertainties have been made for measured and estimated data as well as for various mathematical and physical approximations. Tables of the thermodynamic functions to 6000°K are recommended for gaseous thorium, uranium, and plutonium oxides.
Author: Publisher: ISBN: Category : Languages : en Pages :
Book Description
Measured spectroscopic data, estimated molecular parameters, and a densty-of-states model for electronic structure have been used to calculate thermodynamic functions for gaseous ThO, ThO2, UO, UO2, UO3, PuO, and PuO2. Various methods for estimating parameters have been considered and numerically evaluated. The sensitivity of the calculated thermodynamic functions to molecular parameters has been examined quantitatively. New values of the standard enthalpies of formation at 298.15°K have been derived from the best available .delta. G°/sub f/ equations and the calculated thermodynamic functions. Estimates of the uncertainties have been made for measured and estimated data as well as for various mathematical and physical approximations. Tables of the thermodynamic functions to 6000°K are recommended for gaseous thorium, uranium, and plutonium oxides.
Author: Keith Schofield Publisher: Academic Press ISBN: 0128191279 Category : Technology & Engineering Languages : en Pages : 613
Book Description
Combustion Emissions: Formation, Reaction, and Removal of Trace Metals in Combustion Products presents the latest scientific knowledge on combustion, with a particular focus on the behavior of elements in this high temperature method of energy generation. The book describes methods of control and establishes a solid base of understanding for future research. Encyclopedic in style and consistent in format, each chapter systematically presents a complete analysis of the combustion behavior of each element and guides the reader in resolving specific problems. This includes source levels in fuels and fuel usage, emission and pollutant release into the environment and environmental effects, and more. Societal impacts and environmental concerns are considered throughout, highlighting sustainability aspects across a diverse range of applications, such as within power plants, automobiles and propulsion. - Presents the latest research in a very systematic way - Includes methods of control and establishes a base of understanding for future research in energy systems - Analyzes the individual behavior of 34 elements, considering their chemistry, nature and environmental impacts
Author: Kenneth S Pitzer Publisher: World Scientific ISBN: 9814503983 Category : Science Languages : en Pages : 537
Book Description
In the course of his distinguished career of over 55 years, Kenneth S Pitzer published over 360 scientific papers. Included in this volume are 72 papers, selected for their historical importance and continuing significance. In early work, where spectroscopic data were incomplete or, later on, where the systems of interest were so complex that a deductive solution from molecular information was impractical, Pitzer interrelated molecular structural information, statistical methods and thermodynamic measurements to advance the understanding of molecular systems. This volume considers all three aspects and, by putting together selected papers, highlights the cohesiveness of certain advances through time and development. Several papers from journals not widely circulated can also be found in this selection of papers.
Author: Publisher: Academic Press ISBN: 0128032251 Category : Science Languages : en Pages : 3716
Book Description
This third edition of the Encyclopedia of Spectroscopy and Spectrometry, Three Volume Set provides authoritative and comprehensive coverage of all aspects of spectroscopy and closely related subjects that use the same fundamental principles, including mass spectrometry, imaging techniques and applications. It includes the history, theoretical background, details of instrumentation and technology, and current applications of the key areas of spectroscopy. The new edition will include over 80 new articles across the field. These will complement those from the previous edition, which have been brought up-to-date to reflect the latest trends in the field. Coverage in the third edition includes: Atomic spectroscopy Electronic spectroscopy Fundamentals in spectroscopy High-Energy spectroscopy Magnetic resonance Mass spectrometry Spatially-resolved spectroscopic analysis Vibrational, rotational and Raman spectroscopies The new edition is aimed at professional scientists seeking to familiarize themselves with particular topics quickly and easily. This major reference work continues to be clear and accessible and focus on the fundamental principles, techniques and applications of spectroscopy and spectrometry. Incorporates more than 150 color figures, 5,000 references, and 300 articles for a thorough examination of the field Highlights new research and promotes innovation in applied areas ranging from food science and forensics to biomedicine and health Presents a one-stop resource for quick access to answers and an in-depth examination of topics in the spectroscopy and spectrometry arenas
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Author: United States. National Bureau of Standards
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Author: Keith Schofield
Author: Bonnie J. McBride
Author: Kenneth S Pitzer
Author: Donald D. Wagman
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