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Author: AmyMarie Accardi-Dey Publisher: ISBN: Category : Carbon compounds Languages : en Pages : 304
Book Description
Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) fraction and adsorption onto a combustion-derived, black carbon (BC) fraction. To study BC adsorption, a 375 deg C thermal oxidation method was employed to remove OC and isolate the BC fraction. Test studies showed that nitrogen-containing macromolecules charred during this pretreatment causing a positive bias to the BC measurement. Meanwhile, the oxidation of relatively small BC particles underestimated the total BC content in non-charring samples. Models based on carbon oxidation were then proposed to estimate reasonably the total BC and OC contents of sediment samples. The adsorption of pyrene onto isolated BC particles was then studied by constructing a nonlinear isotherm, which was characterized with a BC-normalized distribution coefficient and a Freundlich exponent. Pyrene sorption to Boston Harbor sediment was then modeled as the sum of OC absorption and BC adsorption using the measured adsorption parameters and literature absorption values. Finally, literature reports of high PAH distribution coefficients from the field and nonlinear PAH isotherms from the laboratory were re-explained by considering BC adsorption.
Author: AmyMarie Accardi-Dey Publisher: ISBN: Category : Carbon compounds Languages : en Pages : 304
Book Description
Sorption is a key factor in determining the fate of polycyclic aromatic hydrocarbons (PAHs) in the environment. Here, PAH sorption is proposed as the sum of two mechanisms: absorption into a biogenic, organic carbon (OC) fraction and adsorption onto a combustion-derived, black carbon (BC) fraction. To study BC adsorption, a 375 deg C thermal oxidation method was employed to remove OC and isolate the BC fraction. Test studies showed that nitrogen-containing macromolecules charred during this pretreatment causing a positive bias to the BC measurement. Meanwhile, the oxidation of relatively small BC particles underestimated the total BC content in non-charring samples. Models based on carbon oxidation were then proposed to estimate reasonably the total BC and OC contents of sediment samples. The adsorption of pyrene onto isolated BC particles was then studied by constructing a nonlinear isotherm, which was characterized with a BC-normalized distribution coefficient and a Freundlich exponent. Pyrene sorption to Boston Harbor sediment was then modeled as the sum of OC absorption and BC adsorption using the measured adsorption parameters and literature absorption values. Finally, literature reports of high PAH distribution coefficients from the field and nonlinear PAH isotherms from the laboratory were re-explained by considering BC adsorption.
Author: Jack J. Middelburg Publisher: Springer ISBN: 3030108228 Category : Science Languages : en Pages : 118
Book Description
This open access book discusses biogeochemical processes relevant to carbon and aims to provide readers, graduate students and researchers, with insight into the functioning of marine ecosystems. A carbon centric approach has been adopted, but other elements are included where relevant or needed. The book focuses on concepts and quantitative understanding of primary production, organic matter mineralization and sediment biogeochemistry. The impact of biogeochemical processes on inorganic carbon dynamics and organic matter transformation are also discussed.
Author: David J. Burdige Publisher: Princeton University Press ISBN: 0691216096 Category : Science Languages : en Pages :
Book Description
The processes occurring in surface marine sediments have a profound effect on the local and global cycling of many elements. This graduate text presents the fundamentals of marine sediment geochemistry by examining the complex chemical, biological, and physical processes that contribute to the conversion of these sediments to rock, a process known as early diagenesis. Research over the past three decades has uncovered the fact that the oxidation of organic matter deposited in sediment acts as a causative agent for many early diagenetic changes. Summarizing and discussing these findings and providing a much-needed update to Robert Berner's Early Diagenesis: A Theoretical Approach, David J. Burdige describes the ways to quantify geochemical processes in marine sediment. By doing so, he offers a deeper understanding of the cycling of elements such as carbon, nitrogen, and phosphorus, along with important metals such as iron and manganese. No other book presents such an in-depth look at marine sediment geochemistry. Including the most up-to-date research, a complete survey of the subject, explanatory text, and the most recent mathematical formulations that have contributed to our greater understanding of early diagenesis, Geochemistry of Marine Sediments will interest graduate students of geology, geochemistry, and oceanography, as well as the broader community of earth scientists. It is poised to become the standard text on the subject for years to come.
Author: Nasa Technical Reports Server (Ntrs) Publisher: BiblioGov ISBN: 9781289292072 Category : Languages : en Pages : 22
Book Description
Dissolved organic matter (DOM) in the ocean constitutes one of the largest pools of organic carbon in the biosphere, yet much of its composition is uncharacterized. Observations of black carbon (BC) particles (by-products of fossil fuel combustion and biomass burning) in the atmosphere, ice, rivers, soils and marine sediments suggest that this material is ubiquitous, yet the contribution of BC to the ocean s DOM pool remains unknown. Analysis of high-molecular-weight DOM isolated from surface waters of two estuaries in the northwest Atlantic Ocean finds that BC is a significant component of DOM, suggesting that river-estuary systems are important exporters of BC to the ocean through DOM. We show that BC comprises 4-7% of the dissolved organic carbon (DOC) at coastal ocean sites, which supports the hypothesis that the DOC pool is the intermediate reservoir in which BC ages prior to sedimentary deposition. Flux calculations suggest that BC could be as important as vascular plant-derived lignin in terms of carbon inputs to the ocean. Production of BC sequesters fossil fuel- and biomass-derived carbon into a refractory carbon pool. Hence, BC may represent a significant sink for carbon to the ocean.
Author: James S. Clark Publisher: Springer Science & Business Media ISBN: 9783540624349 Category : Science Languages : en Pages : 512
Book Description
Biomass burning profoundly affects atmospheric chemistry, the carbon cycle, and climate and may have done so for millions of years. Bringing together renowned experts from paleoecology, fire ecology, atmospheric chemistry, and organic chemistry, the volume elucidates the role of fire during global changes of the past and future. Topics covered include: the characterization of combustion products that occur in sediments, including char, soot/fly ash, and polycyclic aromatic hydrocarbons; the calibration of these constituents against atmospheric measurements from wildland and prescribed fire emissions; spatial and temporal patterns in combustion emissions at scales of individual burns to the globe.
Author: C. Nellemann Publisher: UNEP/Earthprint ISBN: 9788277010601 Category : Law Languages : en Pages : 80
Book Description
This report explores the potential for mitigating the impacts of climate change by improved management and protection of marine ecosystems and especially the vegetated coastal habitat, or blue carbon sinks. The objective of this report is to highlight the critical role of the oceans and ocean ecosystems in maintaining our climate and in assisting policy makers to mainstream an oceans agenda into national and international climate change initiatives. While emissions' reductions are currently at the centre of the climate change discussions, the critical role of the oceans and ocean ecosystems has been vastly overlooked.
Author: AmyMarie Accardi-Dey
Author: AmyMarie Accardi-Dey
Author: Ruediger Stein
Author: Jack J. Middelburg
Author: Edward D. Goldberg
Author: David J. Burdige
Author: Ruediger Stein
Author: Nasa Technical Reports Server (Ntrs)
Author: James S. Clark
Author: Parker Davies Trask
Author: C. Nellemann