Chemical Kinetics and Inorganic Reaction Mechanisms

Chemical Kinetics and Inorganic Reaction Mechanisms PDF Author: Smiljko Asperger
Publisher: Springer Science & Business Media
ISBN: 1441992766
Category : Science
Languages : en
Pages : 363

Book Description
The serious study of the reaction mechanisms of transition metal com plexes began some five decades ago. Work was initiated in the United States and Great Britain; the pioneers ofthat era were, inalphabetical order, F. Basolo, R. E. Connick, 1. O. Edwards, C. S. Garner, G. P.Haight, W. C. E. Higgision, E.1. King, R. G. Pearson, H. Taube, M.1. Tobe, and R. G. Wilkins.A larger community of research scientists then entered the field, many of them stu dents ofthose just mentioned. Interest spread elsewhere as well, principally to Asia, Canada, and Europe. Before long, the results ofindividual studies were being consolidated into models, many of which traced their origins to the better-established field of mechanistic organic chemistry. For a time this sufficed, but major revisions and new assignments of mechanism became necessary for both ligand sub stitution and oxidation-reduction reactions. Mechanistic inorganic chemistry thus took on a shape of its own. This process has brought us to the present time. Interests have expanded both to include new and more complex species (e.g., metalloproteins) and a wealth of new experimental techniques that have developed mechanisms in ever-finer detail. This is the story the author tells, and in so doing he weaves in the identities of the investigators with the story he has to tell. This makes an enjoyable as well as informative reading.

Mechanisms of Inorganic Reactions

Mechanisms of Inorganic Reactions PDF Author: Dimitris Katakis
Publisher: Wiley-Interscience
ISBN:
Category : Medical
Languages : en
Pages : 424

Book Description
Offers complete coverage of basic inorganic reaction mechanisms that brings readers up to date on developments in the field. Mechanistic concepts introduced will provoke consideration of larger categories of inorganic reactions without the need for expert knowledge. Theoretical and experimental methods are described, as well as the possibilities offered by each technique, the kind of information obtained, the limitations of each, and methods for handling experimental data. Carefully clarifies the relationship between mechanism and kinetics, and corresponding concepts. Features a chapter on inorganic photochemistry and the related energy conversion--a branch of inorganic reaction mechanisms that is making rapid advances.

Inorganic Reaction Mechanisms

Inorganic Reaction Mechanisms PDF Author: R. K. Sharma
Publisher: Discovery Publishing House
ISBN: 9788183562263
Category : Chemistry, Inorganic
Languages : en
Pages : 326

Book Description
This book has been designed to cover the syllabus of Inorganic Chemistry required for the B.Sc./B.Sc. Hons./M.Sc. students of the various Universities. I have compelled all the questions asked so far in different universities.. I have arranged the subject matter in a continuous manner. Special emphasis has been laid on fundamental concept of the topics.

Basics of Reaction Mechanism in Inorganic Chemistry

Basics of Reaction Mechanism in Inorganic Chemistry PDF Author: Jayprakash S Chauhan
Publisher: Educreation Publishing
ISBN:
Category : Education
Languages : en
Pages : 138

Book Description
The reading journey of this book starts with very important phenomenon in inorganic chemistry known as the Trans effect. The Trans effect then leads to a very fascinating discovery that changed the whole world. That was the discovery of the anti-cancer drug. The story of its invention is really interesting. This will really trigger the minds of students that how inventions are made. This will show you how one invention leads path to the other. This book introduces the work of Nobel Prize winners and scientist who dedicated their whole life for the sake of chemistry. Henry Taube was awarded the Nobel Prize for his work on complexes & outer and inner sphere reaction mechanism. This book introduces his work. Rudolf A. Marcus received Nobel Prize for his work on redox reactions in complexes. This book discusses the basic principles of redox reactions in complexes. Transition metal complexes plays a fundamental role in three important areas. (1) Bioinorganic chemistry (2) Medicinal chemistry (3) Industrial chemistry. The study of the mechanism helps in designing new inorganic materials, new inorganic catalysts, and new inorganic medicines and for understanding the biological processes. This is a simple book discussing basic principles of inorganic reaction mechanisms. Further, we have provided minor information about basic bioinorganic reactions, nuclear reactions and the chain reaction mechanism. The phenomenon such as acid rain has also been discussed. The last chapter classifies the reactions of metal complexes. Hope this book will be useful for science graduates and post graduates and also for the engineering students.

Reaction Mechanisms of Inorganic and Organometallic Systems

Reaction Mechanisms of Inorganic and Organometallic Systems PDF Author: Robert B. Jordan
Publisher: Oxford University Press
ISBN: 0195301005
Category : Science
Languages : en
Pages : 532

Book Description
This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.

Inorganic and Organometallic Reaction Mechanisms

Inorganic and Organometallic Reaction Mechanisms PDF Author: Jim D. Atwood
Publisher: John Wiley & Sons
ISBN: 0471188972
Category : Science
Languages : en
Pages : 327

Book Description
Jetzt in neuer Auflage: Das erfolgreiche Lehrwerk über Kinetik und Mechanismen anorganischer und organometallischer Reaktionen für fortgeschrittene Studenten! Hervorragend geeignet als Begleiter eines Vorlesungssemesters. Mit zahlreichen Übungsaufgaben; für eine bessere Übersicht sorgen Zusammenfassungen am Ende jedes Kapitels.

Arrow Pushing in Inorganic Chemistry

Arrow Pushing in Inorganic Chemistry PDF Author: Abhik Ghosh
Publisher: John Wiley & Sons
ISBN: 1118924533
Category : Science
Languages : en
Pages : 356

Book Description
Involved as it is with 95% of the periodic table, inorganic chemistry is one of the foundational subjects of scientific study. Inorganic catalysts are used in crucial industrial processes and the field, to a significant extent, also forms the basis of nanotechnology. Unfortunately, the subject is not a popular one for undergraduates. This book aims to take a step to change this state of affairs by presenting a mechanistic, logical introduction to the subject. Organic teaching places heavy emphasis on reaction mechanisms - "arrow-pushing" - and the authors of this book have found that a mechanistic approach works just as well for elementary inorganic chemistry. As opposed to listening to formal lectures or learning the material by heart, by teaching students to recognize common inorganic species as electrophiles and nucleophiles, coupled with organic-style arrow-pushing, this book serves as a gentle and stimulating introduction to inorganic chemistry, providing students with the knowledge and opportunity to solve inorganic reaction mechanisms. • The first book to apply the arrow-pushing method to inorganic chemistry teaching • With the reaction mechanisms approach ("arrow-pushing"), students will no longer have to rely on memorization as a device for learning this subject, but will instead have a logical foundation for this area of study • Teaches students to recognize common inorganic species as electrophiles and nucleophiles, coupled with organic-style arrow-pushing • Provides a degree of integration with what students learn in organic chemistry, facilitating learning of this subject • Serves as an invaluable companion to any introductory inorganic chemistry textbook

The Art of Writing Reasonable Organic Reaction Mechanisms

The Art of Writing Reasonable Organic Reaction Mechanisms PDF Author: Robert B. Grossman
Publisher: Springer Science & Business Media
ISBN: 0387954686
Category : Science
Languages : en
Pages : 371

Book Description
Intended for students of intermediate organic chemistry, this text shows how to write a reasonable mechanism for an organic chemical transformation. The discussion is organized by types of mechanisms and the conditions under which the reaction is executed, rather than by the overall reaction as is the case in most textbooks. Each chapter discusses common mechanistic pathways and suggests practical tips for drawing them. Worked problems are included in the discussion of each mechanism, and "common error alerts" are scattered throughout the text to warn readers about pitfalls and misconceptions that bedevil students. Each chapter is capped by a large problem set.

Inorganic Chemistry

Inorganic Chemistry PDF Author: Harold H. Trimm
Publisher: CRC Press
ISBN: 1926692594
Category : Science
Languages : en
Pages : 334

Book Description
Inorganic chemistry is the study of all chemical compounds except those containing carbon, which is the field of organic chemistry. There is some overlap since both inorganic and organic chemists traditionally study organometallic compounds. Inorganic chemistry has very important ramifications for industry. Current research interests in inorganic chemistry include the discovery of new catalysts, superconductors, and drugs to combat disease. This new volume covers a diverse collection of topics in the field, including new methods to detect unlabeled particles, measurement studies, and more.

Reaction Mechanisms of Metal Complexes

Reaction Mechanisms of Metal Complexes PDF Author: R W Hay
Publisher: Elsevier
ISBN: 1782420630
Category : Technology & Engineering
Languages : en
Pages : 177

Book Description
This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. - Provides a general background as a course module in the area of inorganic reaction mechanisms, which has important research applications in the metallurgical industry - Contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands