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Author: Werner Stumm Publisher: John Wiley & Sons ISBN: 9780471829959 Category : Science Languages : en Pages : 550
Book Description
This comprehensive contributed volume presents an account of current research and applications of chemical processes occurring at the interfaces of water with naturally occuring solids. Interactions of solutes with the solid surfaces are looked at from a mechanistic and dynamic point of view rather than a descriptive one. Processes discussed and concepts presented are applicable to all natural waters (oceans and fresh waters as well as soil and sediment water systems) and to the surfaces of natural solids such as minerals, soils, sediments, biota, and humus. Chapters progress from theoretical models and laboratory studies to applications in natural water, soil, and geochemical systems, emphasizing those processes that regulate the distribution and concentration of elements and compounds. Topics covered include adsorption mechanisms in aquatic surface chemistry, the electric double layer at the solid-solution interface, aspects of molecular structure in surface complexes: spectroscopic investigations, interpretation of metal complexation by heterogeneous complexants, the role of colloids in the partitioning of solutes in natural waters, and 'from molecules to planetary environments': understanding global change.
Author: Werner Stumm Publisher: John Wiley & Sons ISBN: 9780471829959 Category : Science Languages : en Pages : 550
Book Description
This comprehensive contributed volume presents an account of current research and applications of chemical processes occurring at the interfaces of water with naturally occuring solids. Interactions of solutes with the solid surfaces are looked at from a mechanistic and dynamic point of view rather than a descriptive one. Processes discussed and concepts presented are applicable to all natural waters (oceans and fresh waters as well as soil and sediment water systems) and to the surfaces of natural solids such as minerals, soils, sediments, biota, and humus. Chapters progress from theoretical models and laboratory studies to applications in natural water, soil, and geochemical systems, emphasizing those processes that regulate the distribution and concentration of elements and compounds. Topics covered include adsorption mechanisms in aquatic surface chemistry, the electric double layer at the solid-solution interface, aspects of molecular structure in surface complexes: spectroscopic investigations, interpretation of metal complexation by heterogeneous complexants, the role of colloids in the partitioning of solutes in natural waters, and 'from molecules to planetary environments': understanding global change.
Author: Patrick Brezonik Publisher: Oxford University Press ISBN: 019981354X Category : Technology & Engineering Languages : en Pages : 809
Book Description
Water Chemistry provides students with the tools necessary to understand the processes that control the chemical species present in waters of both natural and engineered systems. After providing basic information about water itself and the chemical composition of water in environmental systems, the text covers the necessary theory (thermodynamics, activity, and kinetics) and background material to solve problems. It emphasizes that both equilibrium and kinetic processes are important in aquatic systems. The book does not merely focus on inorganic constituents, but also on the fate and reactions of organic chemicals. The solving of quantitative equilibrium and kinetic problems using mathematical, graphical, and computational tools is emphasized throughout presentations on acid-base chemistry, complexation of metal ions, solubility of minerals, and oxidation-reduction reactions. The use of these problem-solving tools is then extended in the presentation of topics relevant to natural systems, including dissolved oxygen, nutrient chemistry, geochemical controls on chemical composition, photochemistry, and natural organic matter. The kinetics and equilibria relevant to engineered systems (e.g., chlorination and disinfection chemistry, sorption and surface chemistry) and organic contaminant chemistry are also discussed. Numerous in-chapter examples that show the application of theory and demonstrate how problems are solved using algebraic, graphical, and computer-based techniques are included. Examples are relevant to both natural waters and engineered systems.
Author: James N. Jensen Publisher: John Wiley & Sons ISBN: 1119884349 Category : Technology & Engineering Languages : en Pages : 708
Book Description
A Problem-Solving Approach to Aquatic Chemistry Enables civil and environmental engineers to understand the theory and application of aquatic equilibrium chemistry The second edition of A Problem-Solving Approach to Aquatic Chemistry provides a detailed introduction to aquatic equilibrium chemistry, calculation methods for systems at equilibrium, applications of aquatic chemistry, and chemical kinetics. The text directly addresses two required ABET program outcomes in environmental engineering: “… chemistry (including stoichiometry, equilibrium, and kinetics)” and “material and energy balances, fate and transport of substances in and between air, water, and soil phases.” The book is very student-centered, with each chapter beginning with an introduction and ending with a summary that reviews the chapter’s main points. To aid in reader comprehension, important terms are defined in context and key ideas are summarized. Many thought-provoking discussion questions, worked examples, and end of chapter problems are also included. Each part of the text begins with a case study, a portion of which is addressed in each subsequent chapter, illustrating the principles of that chapter. In addition, each chapter has an Historical Note exploring connections with the people and cultures connected to topics in the text. A Problem-Solving Approach to Aquatic Chemistry includes: Fundamental concepts, such as concentration units, thermodynamic basis of equilibrium, and manipulating equilibria Solutions of chemical equilibrium problems, including setting up the problems and algebraic, graphical, and computer solution techniques Acid–base equilibria, including the concepts of acids and bases, titrations, and alkalinity and acidity Complexation, including metals, ligands, equilibrium calculations with complexes, and applications of complexation chemistry Oxidation-reduction equilibria, including equilibrium calculations, graphical approaches, and applications Gas–liquid and solid–liquid equilibrium, with expanded coverage of the effects of global climate change Other topics, including chemical kinetics of aquatic systems, surface chemistry, and integrative case studies For advanced/senior undergraduates and first-year graduate students in environmental engineering courses, A Problem-Solving Approach to Aquatic Chemistry serves as an invaluable learning resource on the topic, with a variety of helpful learning elements included throughout to ensure information retention and the ability to apply covered concepts in practical settings.
Author: Werner Stumm Publisher: Wiley-Interscience ISBN: Category : Nature Languages : en Pages : 464
Book Description
Reflecting the best current thinking and techniques in the field, here is a multi-disciplinary analysis of the dynamics and mechanisms of aquatic systems, using lakes as a point of departure. The contributors, all of whom are recognized world authorities, treat physical, chemical and biological processes such as transport and distribution of chemicals, aquatic surface chemistry, and geobiological cycles of trace elements, which can be applied to all-natural water systems--oceans, rivers and estuaries. Stresses explanation and dynamics rather than documentation.
Author: George R. Helz Publisher: CRC Press ISBN: 135108674X Category : Science Languages : en Pages : 665
Book Description
Aquatic and Surface Photochemistry provides a broad overview of current research in the emerging field of environmental aquatic and surface photochemistry. Selected reviews and current research articles are blended to provide an in-depth treatment of various aspects of this research area. The first part of the text deals with photochemistry in the environment, covering recent research on the following topics: aquatic photochemistry of organic pollutants and agrochemicals, photochemical cycling of carbon and transition metals (especially iron), photochemical formation of reactive oxygen species in natural waters, photoreaction in cloud and rain droplets, and photoreactions on environmental surfaces (soil, ash, metal, oxide). The second part provides discussions and data on both heterogeneous photocatalytic and homogeneous processes, with topics ranging from applications to mechanistic studies. These chapters illustrate the wide diversity of pollutant classes that are degradable by photochemical techniques and the effects of various reaction conditions on the rates and efficiency of the techniques. Current kinetic studies are presented, which provide new information about the role of adsorption and the nature of the reactive oxidizing species that mediate these photoremediation processes.This book will interest civil, chemical, and environmental engineers, as well as chemists, soil scientists, geochemists, and atmospheric chemists.
Author: François Morel Publisher: Wiley-Interscience ISBN: Category : Science Languages : en Pages : 500
Book Description
An introductory text on aquatic chemistry, emphasizing a mathematical, quantitative approach to the field. Covers conservation of mass, thermodynamics and kinetics, chemical equilibrium calculations, acid-base, precipitation-dissolution, coordination, redox, and surface chemistry.
Author: R. Beckett Publisher: Springer Science & Business Media ISBN: 1489925104 Category : Science Languages : en Pages : 163
Book Description
The discipline of surface and colloid chemistIy has experienced a considerable resurgence since the early sixties. This perhaps reflects a growing realisation of the wide applicability of modern colloid and surface theory to many important industrial, medical and environmental problems. This increased activity has resulted in a very complex and at times even confusing area of science being consolidated within a firm theoretical framework. The clearer insights gained into the underlying principles have no doubt acted in an autocatalytic manner to stimulate further interest in an expanding range of applications. A good example in the area of environmental chemistry has been the realization of the important role played by colloidal material and surface interactions in natural biogeochemical processes that has been the subject of increasing attention over the last few decades. This is well illustrated by the numerous studies carried out to elucidate the speciation, toxicity, transport and fate of pollutants in aquatic systems. In the vast majority cases these have clearly implicated some involvement of an aSSOciation between the of pollutant (e. g. trace metal, toxic organic compound or nutrient) and a colloidal component (e. g. particle, humic substance, foam). In order to understand these interactions fully and their effect on pollutant mobility it is important to develop a full appreciation of the surface chemistry of these complex systems. Australian SCientists have long been prominent in the area of colloid and surface chemistry particularly dUring the latter half of this century.
Author: François M. M. Morel Publisher: John Wiley & Sons ISBN: 9780471548966 Category : Science Languages : en Pages : 610
Book Description
Presents aquatic chemistry in a way that is truly useful to those with diverse backgrounds in the sciences. Major improvements to this edition include a complete rewrite of the first three background chapters making them user-friendly. There is less emphasis on mathematics and concepts are illustrated with actual examples to facilitate understanding.