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Author: Hyesung Park (Ph. D.) Publisher: ISBN: Category : Languages : en Pages : 191
Book Description
Graphene, a hexagonal arrangement of carbon atoms forming a one-atom thick planar sheet, has gained much attention due to its remarkable physical properties. Apart from the micromechanical cleavage of highly ordered pyrolytic graphite (HOPG), several alternate methods have been explored to achieve reliable and repeatable synthesis of large-area graphene sheets. Among these, the chemical vapor deposition (CVD) process has been demonstrated as an efficient way of producing continuous, large area graphene films and the synthesis of graphene sheets up to 30-inch has been reported. Similar to graphene research, solar cells based on organic materials have also drawn significant attention as a possible candidate for the generation of clean electricity over conventional inorganic photovoltaics due to the interesting properties of organic semiconductors such as high absorption coefficients, light weight and flexibility, and potentially low-cost, high throughput fabrication processes. Transparent conducting electrodes (TCE) are widely used in organic photovoltaics, and metal oxides such as indium tin oxide (ITO) have been commonly used as window electrodes. Usually used as thin films, these materials require low sheet resistance (Rsh) with high transparency (T). Currently the dominant material used in the industry standard is ITO. However, these materials are not ideal options for organic photovoltaic applications due to several reasons: (1) non-uniform absorption across the visible to near infrared region; (2) chemical instability; (3) metal oxide electrodes easily fracture under large bending, and they are not suitable for flexible solar cell applications; (4) limited availability of indium on the earth leading to increasing costs with time. Therefore, the need for alternative/replacement materials for ITO is ever increasing and ideally need to be developed with the following characteristics: low-cost, mechanically robust, transparent, electrically conductive, and ultimately should demonstrate comparable or better performance compared to ITO-based photovoltaic devices. With superior flexibility and good electrical conductivity, as well as abundance of source material (carbon) at lower costs compared to ITO, in this thesis, we propose that the CVD graphene can be a suitable candidate material as TCE in organic photovoltaic applications, satisfying the aforementioned requirements.
Author: Hyesung Park (Ph. D.) Publisher: ISBN: Category : Languages : en Pages : 191
Book Description
Graphene, a hexagonal arrangement of carbon atoms forming a one-atom thick planar sheet, has gained much attention due to its remarkable physical properties. Apart from the micromechanical cleavage of highly ordered pyrolytic graphite (HOPG), several alternate methods have been explored to achieve reliable and repeatable synthesis of large-area graphene sheets. Among these, the chemical vapor deposition (CVD) process has been demonstrated as an efficient way of producing continuous, large area graphene films and the synthesis of graphene sheets up to 30-inch has been reported. Similar to graphene research, solar cells based on organic materials have also drawn significant attention as a possible candidate for the generation of clean electricity over conventional inorganic photovoltaics due to the interesting properties of organic semiconductors such as high absorption coefficients, light weight and flexibility, and potentially low-cost, high throughput fabrication processes. Transparent conducting electrodes (TCE) are widely used in organic photovoltaics, and metal oxides such as indium tin oxide (ITO) have been commonly used as window electrodes. Usually used as thin films, these materials require low sheet resistance (Rsh) with high transparency (T). Currently the dominant material used in the industry standard is ITO. However, these materials are not ideal options for organic photovoltaic applications due to several reasons: (1) non-uniform absorption across the visible to near infrared region; (2) chemical instability; (3) metal oxide electrodes easily fracture under large bending, and they are not suitable for flexible solar cell applications; (4) limited availability of indium on the earth leading to increasing costs with time. Therefore, the need for alternative/replacement materials for ITO is ever increasing and ideally need to be developed with the following characteristics: low-cost, mechanically robust, transparent, electrically conductive, and ultimately should demonstrate comparable or better performance compared to ITO-based photovoltaic devices. With superior flexibility and good electrical conductivity, as well as abundance of source material (carbon) at lower costs compared to ITO, in this thesis, we propose that the CVD graphene can be a suitable candidate material as TCE in organic photovoltaic applications, satisfying the aforementioned requirements.
Author: Yi Song (Ph. D.) Publisher: ISBN: Category : Languages : en Pages : 142
Book Description
The aim of this thesis is to develop an understanding of the science and engineering in applying chemical vapor deposition (CVD) graphene as the transparent conductor in photovoltaic devices. Transparent conducting oxides currently dominate the transparent conductor market but suffer drawbacks that make them unsuitable certain applications. Graphene is mechanically robust, chemically inert, and has work function that can be tuned by chemical doping, making it a versatile substitute that is compatible many types of devices. We start by demonstrating a scalable method for directly transferring graphene onto a variety of substrates and exploring a doping method that vastly enhances the conductivity of graphene films. These developments improve the attractiveness of CVD graphene for transparent electrode applications. Next, we apply graphene to various types of devices to assess key advantages and challenges. We develop an understanding of the importance of the interface in graphene/silicon Schottky barrier solar cells and apply our understanding to achieve record efficiency in these devices. We also explore graphene/SrTiO3 Schottky junctions, where the graphene itself is responsible for absorbing visible light and show that these devices can be used as tunable photodetectors. We demonstrate highly-transparent organic solar cells with all-graphene electrode as well as inkjet-printed perovskite solar cells with graphene electrodes. Finally, we use graphene/perovskite Schottky barrier solar cells to gain a better understanding of carrier dynamics in perovskite films.
Author: Qingbin Zheng Publisher: Springer ISBN: 1493927698 Category : Technology & Engineering Languages : en Pages : 231
Book Description
This book provides a systematic presentation of the principles and practices behind the synthesis and functionalization of graphene and grapheme oxide (GO), as well as the fabrication techniques for transparent conductors from these materials. Transparent conductors are used in a wide variety of photoelectronic and photovoltaic devices, such as liquid crystal displays (LCDs), solar cells, optical communication devices, and solid-state lighting. Thin films made from indium tin oxide (ITO) have thus far been the dominant source of transparent conductors, and now account for 50% of indium consumption. However, the price of Indium has increased 1000% in the last 10 years. Graphene, a two-dimensional monolayer of sp2-bonded carbon atoms, has attracted significant interest because of its unique transport properties. Because of their high optical transmittance and electrical conductivity, thin film electrodes made from graphene nanosheets have been considered an ideal candidate to replace expensive ITO films. Graphene for Transparent Conductors offers a systematic presentation of the principles, theories and technical practices behind the structure–property relationship of the thin films, which are the key to the successful development of high-performance transparent conductors. At the same time, the unique perspectives provided in the applications of graphene and GO as transparent conductors will serve as a general guide to the design and fabrication of thin film materials for specific applications.
Author: Tae Woo Lee Publisher: Woodhead Publishing ISBN: 0081024835 Category : Technology & Engineering Languages : en Pages : 230
Book Description
Graphene for Next Generation Lighting and Displays provides readers with a comprehensive overview of graphene, flexible graphene electrodes, and graphene-based next-generation display and lighting. The book covers a wide range of information, including the basic physics of graphene and recent trends in technical developments for graphene-based flexible and stretchable light-emitting devices. In addition, it discusses future prospects and suggests further directions for research on graphene-based next-generation displays and lightings. In addition, the book includes sections on the fundamental properties of graphene, synthetic methods of graphene, preparation of graphene electrodes and composite electrodes, and doping methods for graphene electrodes. Potential applications are also addressed including graphene-based flexible electrodes, buffer layer, emitters, and graphene-based stretchable electrodes. Reviews the most promising applications, including OLEDs, graphene-based buffer layers for LEDs, quantum dot emitters, and stretchable graphene electrodes Describes practical approaches in modifying the properties of graphene for the purpose of optoelectronic applications
Author: David Levy Publisher: John Wiley & Sons ISBN: 3527804617 Category : Technology & Engineering Languages : en Pages : 501
Book Description
Der Herausgeber ist ein bekannter Pionier des Fachgebiets mit über 30 Jahren Erfahrung. Dieses Handbuch bietet einen umfassenden Überblick über transparente leitfähige Materialien und legt dabei den Schwerpunkt auf praktische Anwendungen. Nach einer Einführung in die Materialien und jüngsten Entwicklungen werden die Synthese und Charakterisierung sowie Beschichtungsverfahren erläutert, die für die Energiegewinnung und bei lichtemittierenden Anwendungen häufig zum Einsatz kommen. Zukünftige technologische Fortschritte werden am Ende des Buches erörtert. Dieses umfassende und aktuelle interdisziplinäre Fachbuch deckt das komplette Spektrum ab, von der Chemie und den Materialwissenschaften zum Ingenieurswesen, von Lehre und Forschung bis zur Industrie, von den grundlegenden Herausforderungen hin zu direkt verfügbaren Anwendungen.
Author: Arun Kumar Singh Publisher: CRC Press ISBN: 1000368238 Category : Technology & Engineering Languages : en Pages : 233
Book Description
Graphene has many unique properties that have generated tremendous interest in the scientific community and make it suitable for several applications. The tuning of graphene’s Fermi level by the modulation of its charge carriers is an important factor in determining the successful operation of electronic/optoelectronic devices. This book focuses on different methods of performing carrier modulation in graphene and the application of doped graphene in diodes, field-effect transistors, solar cells, transparent conducting electrodes, and supercapacitors. It discusses the current status of the research and development in graphene and will be helpful for readers who want to know about graphene and its applications and also other 2D nanomaterials.
Author: Abdul Rashid bin M. Yusoff Publisher: John Wiley & Sons ISBN: 3527677801 Category : Technology & Engineering Languages : en Pages : 352
Book Description
This first book on emerging applications for this innovative material gives an up-to-date account of the many opportunities graphene offers high-end optoelectronics. The text focuses on potential as well as already realized applications, discussing metallic and passive components, such as transparent conductors and smart windows, as well as high-frequency devices, spintronics, photonics, and terahertz devices. Also included are sections on the fundamental properties, synthesis, and characterization of graphene. With its unique coverage, this book will be welcomed by materials scientists, solid-state chemists and solid-state physicists alike.
Author: Munmaya Mishra Publisher: CRC Press ISBN: 1351019406 Category : Science Languages : en Pages : 6778
Book Description
Undoubtedly the applications of polymers are rapidly evolving. Technology is continually changing and quickly advancing as polymers are needed to solve a variety of day-to-day challenges leading to improvements in quality of life. The Encyclopedia of Polymer Applications presents state-of-the-art research and development on the applications of polymers. This groundbreaking work provides important overviews to help stimulate further advancements in all areas of polymers. This comprehensive multi-volume reference includes articles contributed from a diverse and global team of renowned researchers. It offers a broad-based perspective on a multitude of topics in a variety of applications, as well as detailed research information, figures, tables, illustrations, and references. The encyclopedia provides introductions, classifications, properties, selection, types, technologies, shelf-life, recycling, testing and applications for each of the entries where applicable. It features critical content for both novices and experts including, engineers, scientists (polymer scientists, materials scientists, biomedical engineers, macromolecular chemists), researchers, and students, as well as interested readers in academia, industry, and research institutions.
Author: Mostafizur Rahaman Publisher: Woodhead Publishing ISBN: 0128216409 Category : Technology & Engineering Languages : en Pages : 817
Book Description
Polymer Nanocomposites Containing Graphene: Preparation, Properties and Applications provides detailed up-to-date information on the characterization, synthesis, processing, properties and application of these materials. Key topics that are covered in the book include: the methods of synthesis and preparation of graphene as well as different processes and methods of functionalization and modification of graphene for improving composite properties. The preparation techniques focus on which method is advantageous for getting improvements in properties along with their drawbacks. The structure and property relationships are also discussed in detail. The issues related to graphene dispersion in polymer matrices is also addressed as well as the use of graphene as reinforcement in thermoset resins. The different properties of the composites like mechanical, electrical, dielectric, thermal, rheological, morphology, spectroscopy, electronic, optical, and toxicity are reviewed from the geometrical and functional point of view. Applications cover electrical and electronic fields, flame and fire retardancy, structural, sensing and catalysis, membrane, in fuel cell and solar energy, hydrogen production, aerospace engineering, packaging, and biomedical/bioengineering fields. Up-to-date patents on graphene-polymer nanocomposites are also covered. Those working in graphene-based materials will benefit from the detailed knowledge presented in this book on graphene synthesis, composite preparation methods, and the related problems associated with them. The book will enable researchers to select the appropriate composite as per their respective field of application. Presents novel approaches for the preparation of graphene, its modification and nanocomposites with enhanced properties for state-of-the-art applications Special attention is given to how graphene is synthesized through different routes, their functionality, dispersion related matters and structural aspects controlling the composite properties for various applications All synthesis methodology and functionalization procedure for graphene is discussed
Author: Hyesung Park (Ph. D.)
Author: Hyesung Park (Ph. D.)
Author: Yi Song (Ph. D.)
Author: Qingbin Zheng
Author: Tae Woo Lee
Author: David Levy
Author: George Z. Kyzas
Author: Arun Kumar Singh
Author: Abdul Rashid bin M. Yusoff
Author: Munmaya Mishra
Author: Mostafizur Rahaman