Analytical Pyrolysis of Synthetic Organic Polymers PDF Download

Author: Serban C. Moldoveanu
Publisher: Elsevier
ISBN: 0080455867
Category : Science
Languages : en
Pages : 714

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Book Description
Analytical Pyrolysis of Synthetic Organic Polymers is a follow-up to Analytical Pyrolysis of Natural Organic Polymers, which is volume 20 of the series. The main focus of the book is on practical applications of analytical pyrolysis in synthetic organic polymer identification and characterization. The first part of the book has five chapters including an introduction, a discussion on physico-chemistry of thermal degradation of synthetic polymers and on instrumentation used in analytical pyrolysis, a chapter discussing what type of information can be obtained from analytical pyrolysis, and a chapter dedicated to the analysis and characterization of synthetic polymers.The second part systematically covers the analytical pyrolysis of various classes of synthetic polymers. Some theoretical background for the understanding of polymer structure using analytical pyrolysis is also discussed.* Includes broad coverage of organic synthetic macromolecules* Focuses on physico-chemistry of thermal degradation, and the analytical pyrolysis of various classes of synthetic polymers* Is well written and suitable for both researchers and chemists working in analytical chemistry or in synthetic polymers

Author: Shin Tsuge
Publisher: Elsevier
ISBN: 0444538933
Category : Science
Languages : en
Pages : 405

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Book Description
In this data book, both conventional Py-GC/MS where thermal energy alone is used to cause fragmentation of given polymeric materials and reactive Py-GC/MS in the presence of organic alkaline for condensation polymers are compiled. Before going into detailed presentation of the data, however, acquiring a firm grip on the proper understanding about the situation of Py-GC/MS would promote better utilization of the following pyrolysis data for various polymers samples. This book incorporates recent technological advances in analytical pyrolysis methods especially useful for the characterization of 163 typical synthetic polymers. The book briefly reviews the instrumentation available in advanced analytical pyrolysis, and offers guidance to perform effectually this technique combining with gas chromatography and mass spectrometry. Main contents are comprehensive sample pyrograms, thermograms, identification tables, and representative mass spectra (MS) of pyrolyzates for synthetic polymers. This edition also highlights thermally-assisted hydrolysis and methylation technique effectively applied to 33 basic condensation polymers. - Coverage of Py-GC/MS data of conventional pyrograms and thermograms of basic 163 kinds of synthetic polymers together with MS and retention index data for pyrolyzates, enabling a quick identification - Additional coverage of the pyrograms and their related data for 33 basic condensation polymers obtained by the thermally-assisted hydrolysis and methylation technique - All compiled data measured under the same experimental conditions for pyrolysis, gas chromatography and mass spectrometry to facilitate peak identification - Surveyable instant information on two facing pages dedicated to the whole data of a given polymer sample

Author: S.C. Moldoveanu
Publisher: Elsevier
ISBN: 0128235535
Category : Science
Languages : en
Pages : 642

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Book Description
Analytical Pyrolysis of Natural Organic Polymers, Second Edition, Volume 20 describes the methodology of analytical pyrolysis, the results of pyrolysis for a variety of biopolymers, and several practical applications of analytical pyrolysis on natural organic polymers and their composite materials. The book describes the results of pyrolysis for biopolymers and some chemically modified natural organic polymers. In addition, the many applications of analytical pyrolysis are covered in detail, including topics such as polymer detection used in forensic science, structure elucidation of specific polymers, and identification of small molecules present in polymers (anti-oxidants, plasticizers, etc.). - Assembles all essential information on the pyrolysis of natural polymers in one volume, together with the techniques and instrumentation used - Covers advances and developments over the last 20 years, including discussions on the many different types of apparatus commercially available - Includes reference lists in every chapter to guide readers on a path to further study

Author: Peter Kusch
Publisher: World Scientific
ISBN: 1786345773
Category : Science
Languages : en
Pages : 267

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Book Description
The methodology of analytical pyrolysis-GC/MS has been known for several years, but is seldom used in research laboratories and process control in the chemical industry. This is due to the relative difficulty of interpreting the identified pyrolysis products as well as the variety of them. This book contains full identification of several classes of polymers/copolymers and biopolymers that can be very helpful to the user. In addition, the practical applications can encourage analytical chemists and engineers to use the techniques explored in this volume.The structure and the functions of various types of pyrolyzers and the results of the pyrolysis-gas chromatographic-mass spectrometric identification of synthetic polymers/copolymers and biopolymers at 700°C are described. Practical applications of these techniques are also included, detailing the analysis of microplastics, failure analysis in the automotive industry and solutions for technological problems.

Author: Karen D. Sam
Publisher: CRC Press
ISBN: 0429574924
Category : Science
Languages : en
Pages : 354

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Book Description
Analytical pyrolysis allows scientists to use routine laboratory instrumentation for analyzing complex, opaque, or insoluble samples more effectively than other analytical techniques alone. Analytical Pyrolysis Handbook, Third Edition is a practical guide to the application of pyrolysis techniques to various samples and sample types for a diversity of fields including microbiology, forensic science, industrial research, and environmental analysis. The much-anticipated third edition incorporates recent technological advances that increase the technique’s sensitivity to trace elements, improve its reproducibility, and expand its applicability. The book reviews the types of instrumentation available to perform pyrolysis and offers guidance for interfacing instruments and integrating other analytical techniques, including gas chromatography and mass spectrometry. Fully updated with new sample pyrograms, figures, references, and real-world examples, this edition also highlights new areas of application including cultural materials, forensic analysis, and environmental studies. This book illustrates how the latest advances make pyrolysis a practical, cost-effective, reliable, and flexible alternative for increasingly complex sample analyses. Analytical Pyrolysis Handbook, Third Edition is an essential, one-stop guide for determining if pyrolysis meets application-specific needs as well as performing pyrolysis and handling the data obtained.

Author: Peter Kusch
Publisher: World Scientific
ISBN: 1800613008
Category : Science
Languages : en
Pages : 383

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Book Description
Readers will find many practical applications of pyrolysis-GC/MS as well as R&D usage in this newly revised and expanded edition. Detailed experimental descriptions for the identification of synthetic polymers and copolymers are included. This volume presents the current state of analytical pyrolysis, and contains full identification of several classes of polymers/copolymers and biopolymers that readers will find helpful. Structures and functions of various types of pyrolyzers are explored, as well as the results of the pyrolysis-gas chromatographic-mass spectrometric identification of synthetic polymers/copolymers and biopolymers at 700°C.Practical applications of this hyphenated technique, detailing the analysis of microplastics, failure analysis in the automotive industry and solutions for technological problems are provided. Numerous practical applications of pyrolysis-GC/MS, for industrial and R&D usage, will be of benefit to Chemists and Engineers, as well as for students of Chemistry and Polymer Sciences.

Author: Serban C. Moldoveanu
Publisher: Elsevier
ISBN: 0080932150
Category : Science
Languages : en
Pages : 737

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Book Description
Pyrolysis of Organic Molecules with Applications to Health and Environmental Issues, the 28th volume in the Techniques and Instrumentation in Analytical Chemistry series, gives a systematic and comprehensive description of pyrolysis of non-polymeric organic molecules. Pyrolysis is involved in many practical applications as well as in many common human activities, but harmful compounds can be generated in the process. The study of pyrolysis and of the formation of undesirable compounds as a result of pyrolytic processes is of considerable interest to chemists, chemical engineers, and toxicologists. - Pyrolysis results for compounds not previously studied or reported - Updated information from a large body of results published on pyrolysis of individual compounds or classes of compounds - Information on mechanisms and kinetics of numerous pyrolytic processes

Author: Thomas P. Wampler
Publisher: CRC Press
ISBN: 1420017497
Category : Science
Languages : en
Pages : 302

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Book Description
Analytical pyrolysis allows scientists to use routine laboratory instrumentation for analyzing complex, opaque, or insoluble samples more effectively than other analytical techniques alone. Applied Pyrolysis Handbook, Second Edition is a practical guide to the application of pyrolysis techniques to various samples and sample types for a dive

Author: Peter Kusch
Publisher: BoD – Books on Demand
ISBN: 1789849586
Category : Science
Languages : en
Pages : 104

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Book Description
Analytical pyrolysis deals with the structural identification and quantitation of pyrolysis products with the ultimate aim of establishing the identity of the original material and the mechanisms of its thermal decomposition. The pyrolytic process is carried out in a pyrolyzer interfaced with analytical instrumentation such as gas chromatography (GC), mass spectrometry (MS), gas chromatography coupled with mass spectrometry (GC/MS), or with Fourier-transform infrared spectroscopy (GC/FTIR). By measurement and identification of pyrolysis products, the molecular composition of the original sample can often be reconstructed.This book is the outcome of contributions by experts in the field of pyrolysis and includes applications of the analytical pyrolysis-GC/MS to characterize the structure of synthetic organic polymers and lignocellulosic materials as well as cellulosic pulps and isolated lignins, solid wood, waste particle board, and bio-oil. The thermal degradation of cellulose and biomass is examined by scanning electron micrography, FTIR spectroscopy, thermogravimetry (TG), differential thermal analysis, and TG/MS. The calorimetric determination of high heating values of different raw biomass, plastic waste, and biomass/plastic waste mixtures and their by-products resulting from pyrolysis is described.

Author: Mahmood Barbooti
Publisher: CRC Press
ISBN: 1482262649
Category : Science
Languages : en
Pages : 594

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Book Description
This book is a comprehensive review of the instrumental analytical methods and their use in environmental monitoring site assessment and remediation follow-up operations. The increased concern about environmental issues such as water pollution, air pollution, accumulation of pollutants in food, global climate change, and effective remediation processes necessitate the precise determination of various types of chemicals in environmental samples. In general, all stages of environmental work start with the evaluation of organic and inorganic environmental samples. This important book furnishes the fundamentals of instrumental chemical analysis methods to various environmental applications and also covers recent developments in instrumental chemical methods. Covering a wide variety of topics in the field, the book: • Presents an introduction to environmental chemistry • Presents the fundamentals of instrumental chemical analysis methods that are used mostly in the environmental work. • Examines instrumental methods of analysis including UV/Vis, FTIR, atomic absorption, induced coupled plasma emission, electrochemical methods like potentiometry, voltametry, coulometry, and chromatographic methods such as GC and HPLC • Presents newly introduced chromatographic methodologies such as ion electrophoresis, and combinations of chromatography with pyrolysis methods are given • Discusses selected methods for the determinations of various pollutants in water, air, and land Readers will gain a general review of modern instrumental method of chemical analysis that is useful in environmental work and will learn how to select methods for analyzing certain samples. Analytical instrumentation and its underlying principles are presented, along with the types of sample for which each instrument is best suited. Some noninstrumental techniques, such as colorimetric detection tubes for gases and immnosassays, are also discussed.