Author: Conrad V. Chester
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 86
Book Description
An Investigation of the Transfer of Uranyl Nitrate Across the Water-tributyl Phosphate Interface by the Method of Photographic Photometry
Author: Conrad V. Chester
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 86
Book Description
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 86
Book Description
AN INVESTIGATION OF THE TRANSFER OF URANYL NITRATE ACROSS THE WATER- TRIBUTYL PHOSPHATE INTERFACE BY THE METHOD OF PHOTOGRAPHIC PHOTOMETRY.
Author:
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The resistsnce of the water --tributyl phosphate (TBP) interface to diffusion of uranyl nitrate was investigated by a photographic photometric technique. The resistance was below the limit of detectability in the experiments, even with a surface-active agent present in the system. The sensitivity of the experiments established an upper bound for the interfacial resistance to diffusion equivalent to that of a 25- mu film of TBP under steady- state diffusion. The results indicated that the rate-limiting step in solvent extraction of uranyl nitrate from water by TBP is transfer of the diffusing species between the interface and the bulk phase rather than across the interface. In the experiments a steady-state concentration profile was established across an interface by providing a source of uranyl nitrate on one side and a sink on the other in a special cell. Uranyl nitrate diffused along the concentration gradient and hence across the interface. A resistance to diffusion by the interface would be manifest as a departure from equilibrium of the uranyl concentrations immediately adjacent to and on either side of the interface. Accurate values of the interfacial concentrations at steady state were obtained by extrapolating the profile obtained from a few point measurements on either side. The profiles were computed from densitometric measurements of photographic images of the column which were compared with similar images of standard solutions. (auth).
Publisher:
ISBN:
Category :
Languages : en
Pages :
Book Description
The resistsnce of the water --tributyl phosphate (TBP) interface to diffusion of uranyl nitrate was investigated by a photographic photometric technique. The resistance was below the limit of detectability in the experiments, even with a surface-active agent present in the system. The sensitivity of the experiments established an upper bound for the interfacial resistance to diffusion equivalent to that of a 25- mu film of TBP under steady- state diffusion. The results indicated that the rate-limiting step in solvent extraction of uranyl nitrate from water by TBP is transfer of the diffusing species between the interface and the bulk phase rather than across the interface. In the experiments a steady-state concentration profile was established across an interface by providing a source of uranyl nitrate on one side and a sink on the other in a special cell. Uranyl nitrate diffused along the concentration gradient and hence across the interface. A resistance to diffusion by the interface would be manifest as a departure from equilibrium of the uranyl concentrations immediately adjacent to and on either side of the interface. Accurate values of the interfacial concentrations at steady state were obtained by extrapolating the profile obtained from a few point measurements on either side. The profiles were computed from densitometric measurements of photographic images of the column which were compared with similar images of standard solutions. (auth).
Atomic Energy Research Reports for Sale by the U.S. Department of Commerce, Office of Technical Services
Author: Business and Defense Services Administration
Publisher:
ISBN:
Category :
Languages : en
Pages : 68
Book Description
Publisher:
ISBN:
Category :
Languages : en
Pages : 68
Book Description
Chemical Technology Division Annual Progress Report
Author: Oak Ridge National Laboratory. Chemical Technology Division
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages : 174
Book Description
Publisher:
ISBN:
Category : Chemical engineering
Languages : en
Pages : 174
Book Description
Nuclear Science Abstracts
Publications, Reports, and Papers for 1961- from Oak Ridge National Laboratory
Author: Oak Ridge National Laboratory
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 94
Book Description
Publisher:
ISBN:
Category : Government publications
Languages : en
Pages : 94
Book Description
Bibliography of the Literature of the Health Physics Division Through Calendar Year 1975
Author:
Publisher:
ISBN:
Category : Medical physics
Languages : en
Pages : 290
Book Description
Over 2000 references to publications (also including miscellaneous reports, patents, and theses) of staff members of Health Physics Division during 1945-1975. "Useful in tracing the growth and development of the health physics profession."Basic chronological arrangement by years. Patents and theses listed separately. Besides bibliographical information, each entry includes identification code number indicating year of publication, document number, and kind of publication.
Publisher:
ISBN:
Category : Medical physics
Languages : en
Pages : 290
Book Description
Over 2000 references to publications (also including miscellaneous reports, patents, and theses) of staff members of Health Physics Division during 1945-1975. "Useful in tracing the growth and development of the health physics profession."Basic chronological arrangement by years. Patents and theses listed separately. Besides bibliographical information, each entry includes identification code number indicating year of publication, document number, and kind of publication.
Proceedings of the International Solvent Extraction Conference, I. S. E. C. 74, Lyon, 8-14th September 1974
Author:
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 942
Book Description
Publisher:
ISBN:
Category : Extraction (Chemistry)
Languages : en
Pages : 942
Book Description
Publications, Reports and Papers
Author: Oak Ridge National Laboratory
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 94
Book Description
Publisher:
ISBN:
Category : Nuclear energy
Languages : en
Pages : 94
Book Description