Author: M. A. Henderson
Publisher:
ISBN:
Category :
Languages : en
Pages : 14
Book Description
An infrared study has been performed concerning the possible dissociation of CO2 on supported Rh catalyst films. The data indicate that CO2 does dissociate on Rh/TiO2 and Rh/Al2O3 to form a carbonyl hydride species in accord with the work of Solymosi. This dissociation process is considerably enhanced by the presence of a small amount of hydrogen gas, but will proceed in the absence of hydrogen gas with the assistance of hydrogen migration from the support. Impurity boron also enhances the formation of the carbonyl hydride species, and hence CO2 dissociation, when it is present in the supported Rh films. Author finished keywords: Infrared spectroscopy, Carbon dioxide, Methanation, Supported rhodium catalysts.
An Infrared Study of the Dissociation of Carbon Dioxide Over Supported Rhodium Catalysts
Author: M. A. Henderson
Publisher:
ISBN:
Category :
Languages : en
Pages : 14
Book Description
An infrared study has been performed concerning the possible dissociation of CO2 on supported Rh catalyst films. The data indicate that CO2 does dissociate on Rh/TiO2 and Rh/Al2O3 to form a carbonyl hydride species in accord with the work of Solymosi. This dissociation process is considerably enhanced by the presence of a small amount of hydrogen gas, but will proceed in the absence of hydrogen gas with the assistance of hydrogen migration from the support. Impurity boron also enhances the formation of the carbonyl hydride species, and hence CO2 dissociation, when it is present in the supported Rh films. Author finished keywords: Infrared spectroscopy, Carbon dioxide, Methanation, Supported rhodium catalysts.
Publisher:
ISBN:
Category :
Languages : en
Pages : 14
Book Description
An infrared study has been performed concerning the possible dissociation of CO2 on supported Rh catalyst films. The data indicate that CO2 does dissociate on Rh/TiO2 and Rh/Al2O3 to form a carbonyl hydride species in accord with the work of Solymosi. This dissociation process is considerably enhanced by the presence of a small amount of hydrogen gas, but will proceed in the absence of hydrogen gas with the assistance of hydrogen migration from the support. Impurity boron also enhances the formation of the carbonyl hydride species, and hence CO2 dissociation, when it is present in the supported Rh films. Author finished keywords: Infrared spectroscopy, Carbon dioxide, Methanation, Supported rhodium catalysts.
An Infrared Study of the Hydrogenation of Carbon Dioxide on Supported Rhodium Catalysts
Author: M. A. Henderson
Publisher:
ISBN:
Category :
Languages : en
Pages : 37
Book Description
An infrared study of the methanation of CO2 on supported Rh catalysts has been performed. This reaction has been shown to occur over these catalysts with higher turnover frequency at a given temperature and Rh loading than does the methanation of CO. A support effect has been demonstrated for the reaction over the supported Rh catalysts (TiO2 Al2O3 SiO2 in reactivity). A key surface intermediate during the methanation reaction is a carbonyl hydride species, as evidenced by a prominent infrared band in the 2020-2040/cm region which shifts by 5-10/cm when D2 is substituted for H2 in the reaction mixture. This carbonyl hydride species can be produced in the absence of H2 by migration of H from the support to Rh. The dissociation of CO2 on supported Rh has been shown to be enhanced by the presence of H2 and impurity boron. Originator-supplied keywords include: Infrared spectroscopy, Carbon dioxide, Hydrogenation, Methanation, and Supported rhodium catalysts.
Publisher:
ISBN:
Category :
Languages : en
Pages : 37
Book Description
An infrared study of the methanation of CO2 on supported Rh catalysts has been performed. This reaction has been shown to occur over these catalysts with higher turnover frequency at a given temperature and Rh loading than does the methanation of CO. A support effect has been demonstrated for the reaction over the supported Rh catalysts (TiO2 Al2O3 SiO2 in reactivity). A key surface intermediate during the methanation reaction is a carbonyl hydride species, as evidenced by a prominent infrared band in the 2020-2040/cm region which shifts by 5-10/cm when D2 is substituted for H2 in the reaction mixture. This carbonyl hydride species can be produced in the absence of H2 by migration of H from the support to Rh. The dissociation of CO2 on supported Rh has been shown to be enhanced by the presence of H2 and impurity boron. Originator-supplied keywords include: Infrared spectroscopy, Carbon dioxide, Hydrogenation, Methanation, and Supported rhodium catalysts.
An Infrared Study of Isotopic Exchange During Methanation Over Supported Rhodium Catalysts; An Inverse Spillover Effect
Author: M. A. Henderson
Publisher:
ISBN:
Category :
Languages : en
Pages : 15
Book Description
Infrared spectroscopy has been employed to study the reduction of carbon dioxide on supported catalyst films. The investigation included isotopic labeling using deuterium as the reduction gas. Isotopic exchange was observed for both carbon dioxide/D2 and methane/deuterium mixtures. The mechanism of this isotopic exchange involves migration of hydrogen from the support to the rhodium sites, an inverse spillover effect. A key intermediate in the dissociation of carbon dioxide on the supported Rh films was a carbonyl hydride species.
Publisher:
ISBN:
Category :
Languages : en
Pages : 15
Book Description
Infrared spectroscopy has been employed to study the reduction of carbon dioxide on supported catalyst films. The investigation included isotopic labeling using deuterium as the reduction gas. Isotopic exchange was observed for both carbon dioxide/D2 and methane/deuterium mixtures. The mechanism of this isotopic exchange involves migration of hydrogen from the support to the rhodium sites, an inverse spillover effect. A key intermediate in the dissociation of carbon dioxide on the supported Rh films was a carbonyl hydride species.
An Infrared Study of the Oxidation of Carbon Monoxide Over Supported Rhodium Catalysts
Author: C. H. Dai
Publisher:
ISBN:
Category :
Languages : en
Pages : 19
Book Description
The reaction of carbon monoxide and oxygen over supported rhodium films has been studied using infrared spectroscopy. The focus of work was the reactivity of the various CO/Rh/X (X=Al2O3, SiO2, TiO2) surface states for supported catalysts having high and low Rh loading. Under the reaction conditions the 'linear CO' species was the most stable toward oxidation, but this could have been a result of an oxidized Rh surface. A new CO/Rh surface species has been proposed which exhibits an infrared band at 2000/cm for a 0.5% Rh/TiO2 film. This species is believed to be a bridged carbonyl between Rh+1 and the TiO2 support. Originator-supplied keywords include: Infrared spectroscopy, and Carbon dioxide.
Publisher:
ISBN:
Category :
Languages : en
Pages : 19
Book Description
The reaction of carbon monoxide and oxygen over supported rhodium films has been studied using infrared spectroscopy. The focus of work was the reactivity of the various CO/Rh/X (X=Al2O3, SiO2, TiO2) surface states for supported catalysts having high and low Rh loading. Under the reaction conditions the 'linear CO' species was the most stable toward oxidation, but this could have been a result of an oxidized Rh surface. A new CO/Rh surface species has been proposed which exhibits an infrared band at 2000/cm for a 0.5% Rh/TiO2 film. This species is believed to be a bridged carbonyl between Rh+1 and the TiO2 support. Originator-supplied keywords include: Infrared spectroscopy, and Carbon dioxide.
Scientific and Technical Aerospace Reports
An Infrared Study of Supported Rhodium Catalysts
Author: Chi-Hun Dai
Publisher:
ISBN:
Category : Infrared spectroscopy
Languages : en
Pages : 296
Book Description
Publisher:
ISBN:
Category : Infrared spectroscopy
Languages : en
Pages : 296
Book Description
Properties and Applications of Perovskite-Type Oxides
Author: L.G. Tejuca
Publisher: CRC Press
ISBN: 9781439855225
Category : Science
Languages : en
Pages : 404
Book Description
This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.
Publisher: CRC Press
ISBN: 9781439855225
Category : Science
Languages : en
Pages : 404
Book Description
This reference offers an overview of the bulk and surface properties of perovskite-like structures, and provides the latest discussions on the applications of these materials and processes. It also introduces ceramic methods for the processing of perovskite-derived high Tc cuprates.;Examining every available procedure for synthesizing high-surface-area perovskite oxides, this book: delineates processing techniques for preparing perovskite-derived high-critical-temperature superconductors; illustrates the relevance of physiochemical methods to investigate bulk and surface structures of perovskite compounds; explicates the importance of surface composition in the context of catalytic behaviour; summarizes methods of changing stoichiometry; shows how to design perovskite oxides for a given purpose; reviews key solid-state properties; and presents the major applications.
Infrared Study of the Surface Interaction Between H2 and CO2 Over Rhodium on Various Supports
Infrared Studies of Supported Rhodium Catalysts
Author: James A. Anderson
Publisher:
ISBN:
Category : Infrared spectroscopy
Languages : en
Pages :
Book Description
Publisher:
ISBN:
Category : Infrared spectroscopy
Languages : en
Pages :
Book Description