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Author: Donald T. Reed Publisher: Springer Science & Business Media ISBN: 1441986901 Category : Technology & Engineering Languages : en Pages : 267
Book Description
The management and disposal of radioactive wastes are key international issues requiring a sound, fundamental scientific basis to insure public and environmental protection. Large quantities of existing nuclear waste must be treated to encapsulate the radioactivity in a form suitable for disposal. The treatment of this waste, due to its extreme diversity, presents tremendous engineering and scientific challenges. Geologic isolation of transuranic waste is the approach currently proposed by all nuclear countries for its final disposal. To be successful in this endeavor, it is necessary to understand the behavior of plutonium and the other actinides in relevant environmental media. Conceptual models for stored high level waste and waste repository systems present many sCientific difficulties due to their complexity and non-ideality. For example, much of the high level nuclear waste in the US is stored as alkaline concentrated electrolyte materials, where the chemistry of the actinides under such conditions is not well understood. This lack of understanding limits the successful separation and treatment of these wastes. Also, countries such as the US and Germany plan to dispose of actinide bearing wastes in geologic salt deposits. In this case, understanding the speciation and transport properties of actinides in brines is critical for confidence in repository performance and risk assessment activities. Many deep groundwaters underlying existing contaminated sites are also high in ionic strength. Until recently, the scientific basis for describing actinide chemistry in such systems was extremely limited.
Author: Donald T. Reed Publisher: Springer Science & Business Media ISBN: 1441986901 Category : Technology & Engineering Languages : en Pages : 267
Book Description
The management and disposal of radioactive wastes are key international issues requiring a sound, fundamental scientific basis to insure public and environmental protection. Large quantities of existing nuclear waste must be treated to encapsulate the radioactivity in a form suitable for disposal. The treatment of this waste, due to its extreme diversity, presents tremendous engineering and scientific challenges. Geologic isolation of transuranic waste is the approach currently proposed by all nuclear countries for its final disposal. To be successful in this endeavor, it is necessary to understand the behavior of plutonium and the other actinides in relevant environmental media. Conceptual models for stored high level waste and waste repository systems present many sCientific difficulties due to their complexity and non-ideality. For example, much of the high level nuclear waste in the US is stored as alkaline concentrated electrolyte materials, where the chemistry of the actinides under such conditions is not well understood. This lack of understanding limits the successful separation and treatment of these wastes. Also, countries such as the US and Germany plan to dispose of actinide bearing wastes in geologic salt deposits. In this case, understanding the speciation and transport properties of actinides in brines is critical for confidence in repository performance and risk assessment activities. Many deep groundwaters underlying existing contaminated sites are also high in ionic strength. Until recently, the scientific basis for describing actinide chemistry in such systems was extremely limited.
Author: Joseph A. Caruso Publisher: John Wiley & Sons ISBN: 9780470855980 Category : Science Languages : en Pages : 808
Book Description
Written by an internationally recognized group of editors and contributors, Handbook of Elemental Speciation, Volume 2 provides a comprehensive, cross-disciplinary presentation of the analytical techniques involved in speciation. Comprehensive coverage of key elements and compounds in situ Addresses the analysis and impact of these elements and compounds, e.g. arsenic, lead, copper, iron, halogens, etc., in food, the environment, clinical and occupational health Detailed methodology and data are reported, as well as regulatory limits Includes general introduction on the impact in these key areas
Author: Heinrich D Holland Publisher: Academic Press ISBN: 0123813921 Category : Science Languages : en Pages : 681
Book Description
Readings from the Treatise on Geochemistry offers an interdisciplinary reference for scientists, researchers and upper undergraduate and graduate level geochemistry students that is more affordable than the full Treatise. For professionals, this volume will provide an overview of the field as a whole. For students, it will provide more in-depth introductory content than is found in broad-based geochemistry textbooks. Articles were selected from chapters across all volumes of the full Treatise, and include: The Origin and Earliest History of the Earth, Compositional Evolution of the Mantle, Evolution of Sedimentary Rocks, Soil Formation, Geochemistry of Groundwater, Geologic History of Seawater, Hydrothermal Processes, and Biogeochemistry of Primary Production in the Sea. Comprehensive, interdisciplinary and authoritative content selected by leading subject experts Robust illustrations, figures and tables Affordably priced sampling of content from the full Treatise on Geochemistry
Author: B. Sherwood Lollar Publisher: Elsevier ISBN: 9780080446431 Category : Medical Languages : en Pages : 652
Book Description
The Treatise on Geochemistry is the first work providing a comprehensive, integrated summary of the present state of geochemistry. It deals with all the major subjects in the field, ranging from the chemistry of the solar system to environmental geochemistry. The Treatise on Geochemistry has drawn on the expertise of outstanding scientists throughout the world, creating the reference work in geochemistry for the next decade. Each volume consists of fifteen to twenty-five chapters written by recognized authorities in their fields, and chosen by the Volume Editors in consultation with the Executive Editors. Particular emphasis has been placed on integrating the subject matter of the individual chapters and volumes. Elsevier also offers the Treatise on Geochemistry in electronic format via the online platform ScienceDirect, the most comprehensive database of academic research on the Internet today, enhanced by a suite of sophisticated linking, searching and retrieval tools.
Author: L.R. Morss Publisher: Springer Science & Business Media ISBN: 9400702116 Category : Science Languages : en Pages : 4511
Book Description
The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts. The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements contain partially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.
Author: L.R. Morss Publisher: Springer Science & Business Media ISBN: 1402035985 Category : Science Languages : en Pages : 4059
Book Description
The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.
Author: Publisher: Elsevier ISBN: 0080457525 Category : Science Languages : en Pages : 1133
Book Description
This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for compounds of complexes of oxalate, citrate, EDTA and iso-saccharinate with uranium, neptunium, plutonium, americium, technetium, selenium, nickel and zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography.Contributed by: Wolfgang Hummel (Chairman), Paul Scherrer Institute, Switzerland, Giorgio Anderegg, Swiss Federal Institute of Technology (ETH), Switzerland, Linfeng Rao, Lawrence Berkeley National Laboratory, U.S.A., Ignasi Puigdomènech, Swedish Nuclear Fuel and Waste Management Co. (SKB), Sweden, and Osamu Tochiyama, Tohoku University, Japan.* Critical review of all literature on chemical thermodynamics for compounds and complexes of oxalate, citrate, EDTA and iso-saccharinate with U, Np, Pu, Am, Tc and Se, Ni and Zr.* Tables of recommended Selected Values for thermochemical properties* Documented review procedure* Exhaustive bibliography* Intended to meet requirements of radioactive waste management community* Valuable reference source for the physical, analytical and environmental chemist.
Author: Reid Peterson Publisher: CRC Press ISBN: 0429882556 Category : Science Languages : en Pages : 345
Book Description
Engineering Separations Unit Operations for Nuclear Processing provides insight into the fundamentals of separations in nuclear materials processing not covered in typical texts. This book integrates fuel cycle and waste processing into a single, coherent approach, demonstrating that the principles from one field can and should be applied to the other. It provides historical perspectives on nuclear materials processing, current assessment and challenges, and how past challenges were overcome. It also provides understanding of the engineering principles associated with handling nuclear materials. This book is aimed at researchers, graduate students, and professionals in the fields of chemical engineering, mechanical engineering, nuclear engineering, and materials engineering.
Author: Jonathan R. Lloyd Publisher: Elsevier ISBN: 0128186968 Category : Science Languages : en Pages : 378
Book Description
The Microbiology of Nuclear Waste Disposal is a state-of-the-art reference featuring contributions focusing on the impact of microbes on the safe long-term disposal of nuclear waste. This book is the first to cover this important emerging topic, and is written for a wide audience encompassing regulators, implementers, academics, and other stakeholders. The book is also of interest to those working on the wider exploitation of the subsurface, such as bioremediation, carbon capture and storage, geothermal energy, and water quality. Planning for suitable facilities in the U.S., Europe, and Asia has been based mainly on knowledge from the geological and physical sciences. However, recent studies have shown that microbial life can proliferate in the inhospitable environments associated with radioactive waste disposal, and can control the long-term fate of nuclear materials. This can have beneficial and damaging impacts, which need to be quantified. - Encompasses expertise from both the bio and geo disciplines, aiming to foster important collaborations across this disciplinary divide - Includes reviews and research papers from leading groups in the field - Provides helpful guidance in light of plans progressing worldwide for geological disposal facilities - Includes timely research for planning and safety case development
Author: Donald T. Reed
Author: Donald T. Reed
Author: Joseph A. Caruso
Author: Heinrich D Holland
Author: B. Sherwood Lollar
Author: L.R. Morss
Author: L.R. Morss
Author: 
Author: Reid Peterson
Author: Jonathan R. Lloyd
Author: Heinrich D. Holland