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Author: Sergey Krivovichev Publisher: Elsevier ISBN: 0080467911 Category : Science Languages : en Pages : 505
Book Description
Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'
Author: Sergey Krivovichev Publisher: Elsevier ISBN: 0080467911 Category : Science Languages : en Pages : 505
Book Description
Structural Chemistry of Inorganic Actinide Compounds is a collection of 13 reviews on structural and coordination chemistry of actinide compounds. Within the last decade, these compounds have attracted considerable attention because of their importance for radioactive waste management, catalysis, ion-exchange and absorption applications, etc. Synthetic and natural actinide compounds are also of great environmental concern as they form as a result of alteration of spent nuclear fuel and radioactive waste under Earth surface conditions, during burn-up of nuclear fuel in reactors, represent oxidation products of uranium miles and mine tailings, etc. The actinide compounds are also of considerable interest to material scientists due to the unique electronic properties of actinides that give rise to interesting physical properties controlled by the structural architecture of respective compounds. The book provides both general overview and review of recent developments in the field, including such emergent topics as nanomaterials and nanoparticles and their relevance to the transfer of actinides under environmental conditions.* Covers over 2,000 actinide compounds including materials, minerals and coordination polymers* Summarizes recent achievements in the field* Some chapters reveal (secret) advances made by the Soviet Union during the 'Cold war'
Author: Z. Marczenko Publisher: Elsevier ISBN: 0080541089 Category : Science Languages : en Pages : 526
Book Description
Spectrophotometry enables one to determine, with good precision and sensitivity, almost all the elements present in small and trace quantities of any material. The method is particularly useful in the determination of non-metals and allows the determination elements in a large range of concentrations (from single % to low ppm levels) in various materials.In Separation, Preconcentration and Spectrophotometry in Inorganic Analysis, much attention has been paid to separation and preconcentration methods, since they play an essential role in increasing the selectivity and sensitivity of spectrophotometric methods. Separation and preconcentration methods have also been utilised in other determination techniques.Spectrophotometric methods which are widely used for the determination of the elements in a large variety of inorganic materials are presented in the book whilst separation and preconcentration procedures combined with spectrophotometry are also described. This book contains recent advances in spectrophotometry, detailed discussion of the instrumentation, and the techniques and reagents used for spectrophotometric determination of elements in a wide range of materials as well as a detailed discussion of separation and preconcentration procedures that precede the spectrophotometric detection.
Author: John Emsley Publisher: Oxford University Press, USA ISBN: 9780198503408 Category : Science Languages : en Pages : 556
Book Description
A readable, informative, fascinating entry on each one of the 100-odd chemical elements, arranged alphabetically from actinium to zirconium. Each entry comprises an explanation of where the element's name comes from, followed by Body element (the role it plays in living things), Element ofhistory (how and when it was discovered), Economic element (what it is used for), Environmental element (where it occurs, how much), Chemical element (facts, figures and narrative), and Element of surprise (an amazing, little-known fact about it). A wonderful 'dipping into' source for the familyreference shelf and for students.
Author: Ingmar Grenthe Publisher: Elsevier Science & Technology ISBN: Category : Science Languages : en Pages : 744
Book Description
This volume provides a comprehensive overview on the chemical thermodynamics of those elements that are of particular importance in the safety assessment of radioactive waste disposal systems. This is the first volume in a series of critical reviews to be published on this subject. The book provides an extensive compilation of chemical thermodynamic data for uranium. A description of procedures for activity corrections and uncertainty estimates is given. A critical discussion of data needed for nuclear waste management assessments, including areas where significant gaps of knowledge exist is presented. A detailed inventory of chemical thermodynamic data for inorganic compounds and complexes of uranium is listed. Data and their uncertainty limits are recommended for 74 aqueous complexes and 199 solid and 31 gaseous compounds containing uranium, and on 52 aqueous and 17 solid auxiliary species containing no uranium. The data are internally consistent and compatible with the CODATA Key Values. The book contains a detailed discussion of procedures used for activity factor corrections in aqueous solution, as well as including methods for making uncertainty estimates.
Author: National Research Council Publisher: National Academies Press ISBN: 0309087228 Category : Science Languages : en Pages : 124
Book Description
The production of nuclear materials for the national defense was an intense, nationwide effort that began with the Manhattan Project and continued throughout the Cold War. Now many of these product materials, by-products, and precursors, such as irradiated nuclear fuels and targets, have been declared as excess by the Department of Energy (DOE). Most of this excess inventory has been, or will be, turned over to DOE's Office of Environmental Management (EM), which is responsible for cleaning up the former production sites. Recognizing the scientific and technical challenges facing EM, Congress in 1995 established the EM Science Program (EMSP) to develop and fund directed, long-term research that could substantially enhance the knowledge base available for new cleanup technologies and decision making. The EMSP has previously asked the National Academies' National Research Council for advice for developing research agendas in subsurface contamination, facility deactivation and decommissioning, high-level waste, and mixed and transuranic waste. For this study the committee was tasked to provide recommendations for a research agenda to improve the scientific basis for DOE's management of its high-cost, high-volume, or high-risk excess nuclear materials and spent nuclear fuels. To address its task, the committee focused its attention on DOE's excess plutonium-239, spent nuclear fuels, cesium-137 and strontium-90 capsules, depleted uranium, and higher actinide isotopes.
Author: Gregory Choppin Publisher: Butterworth-Heinemann ISBN: 0750674636 Category : Science Languages : en Pages : 726
Book Description
Origin of Nuclear Science; Nuclei, Isotopes and Isotope Separation; Nuclear Mass and Stability; Unstable Nuclei and Radioactive Decay; Radionuclides in Nature; Absorption of Nuclear Radiation; Radiation Effects on Matter; Detection and Measurement Techniques; Uses of Radioactive Tracers; Cosmic Radiation and Elementary Particles; Nuclear Structure; Energetics of Nuclear Reactions; Particle Accelerators; Mechanics and Models of Nuclear Reactions; Production of Radionuclides; The Transuranium Elements; Thermonuclear Reactions: the Beginning and the Future; Radiation Biology and Radiation Protection; Principles of Nuclear Power; Nuclear Power Reactors; Nuclear Fuel Cycle; Behavior of Radionuclides in the Environment; Appendices; Solvent Extraction Separations; Answers to Exercises; Isotope Chart; Periodic Table of the Elements; Quantities and Units; Fundamental Constants; Energy Conversion Factors; Element and Nuclide Index; Subject Index.
Author: L.R. Morss Publisher: Springer Science & Business Media ISBN: 1402035985 Category : Science Languages : en Pages : 4059
Book Description
The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.
Author: Sergey Krivovichev
Author: Sergey Krivovichev
Author: L. J. Brady
Author: Z. Marczenko
Author: John Emsley
Author: Ingmar Grenthe
Author: National Research Council
Author: Gregory Choppin
Author: 
Author: Geological Survey (U.S.)
Author: L.R. Morss