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A Mechanism Study of Nanoparticles for Enhanced Oil Recovery

A Mechanism Study of Nanoparticles for Enhanced Oil Recovery PDF Author: Renfeng Jiang
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
The application of nanotechnology in enhanced oil recovery (EOR) is emerging because nanoparticles have the potential to alter rock properties like wettability and fluid properties such as interfacial tension (IFT). In addition, a newly-proposed theory of the structural disjoining pressure (SDP) has become popular in the scientific community as well. However, a systematic literature review shows that ambiguity exists regarding which components in nanofluid play the role of changing wettability and interfacial tension (IFT). In addition, there are only a limited number of numerical and experimental studies to investigate the theory of the structural disjoining pressure (SDP), none of which can strictly confirm the theory. This motivates us to study these potential candidates of the mechanisms of nano-enhanced oil recovery (nano-EOR). We first conducted experiments using the contact angle goniometer to measure the contact angle and the interfacial tension (IFT) for various nanofluid compositions and the results showed that the addition of bare silica nanoparticles could reduce the contact angle. Specifically, a reduction in nanoparticle size and an increase in nanofluid concentration could further reduce the contact angle. However, bare nanoparticles did not change the interfacial tension (IFT). In order to investigate the theory of the structural disjoining pressure (SDP), we extended the model with a configuration that simulates the real case of the detachment of an oil droplet. The results showed that four conditions favor the spreading of the nanofluid on the substrate and the detachment of the oil droplet from the substrate to which it attached due to the structural disjoining pressure (SDP). These conditions include a high nanofluid concentration, a small nanoparticle size, a small contact angle of the nanofluid/oil/substrate system looking from the nanofluid phase, and a large oil droplet. Three imaging experiments were conducted using environmental scanning electron microscopy (ESEM) and dynamic fluid-film interferometry (DFI) to verify the theory of nanofluid spreading due to the structural disjoining pressure (SDP). ESEM imaging experiments showed the result of a single layer of nanoparticles but could not eliminate the effect of evaporation. Combining the ESEM images with the results from DFI in a liquid cell eliminated the evaporation effect and confirmed that nanoparticles are capable of spreading over the substrate in a thin film that is composed of one single layer of nanoparticles. Moreover, an experiment into the extension of the coffee ring effect showed the discovery of a new coffee ring pattern. Finally, we conducted a nanofluid flooding experiment using carbonate rocks. It was able to isolate the effect of the two confirmed mechanisms on the oil recovery rate at core-scale and tested the potential of nano-enhanced oil recovery (nano-EOR) at core-scale. We determined that an increase in oil recovery of 6% was due to the wettability alteration and another 6% increase in oil recovery was due to the mechanism of the structural disjoining pressure (SDP) for our low permeable carbonate core.

A Mechanism Study of Nanoparticles for Enhanced Oil Recovery

A Mechanism Study of Nanoparticles for Enhanced Oil Recovery PDF Author: Renfeng Jiang
Publisher:
ISBN:
Category :
Languages : en
Pages :

Book Description
The application of nanotechnology in enhanced oil recovery (EOR) is emerging because nanoparticles have the potential to alter rock properties like wettability and fluid properties such as interfacial tension (IFT). In addition, a newly-proposed theory of the structural disjoining pressure (SDP) has become popular in the scientific community as well. However, a systematic literature review shows that ambiguity exists regarding which components in nanofluid play the role of changing wettability and interfacial tension (IFT). In addition, there are only a limited number of numerical and experimental studies to investigate the theory of the structural disjoining pressure (SDP), none of which can strictly confirm the theory. This motivates us to study these potential candidates of the mechanisms of nano-enhanced oil recovery (nano-EOR). We first conducted experiments using the contact angle goniometer to measure the contact angle and the interfacial tension (IFT) for various nanofluid compositions and the results showed that the addition of bare silica nanoparticles could reduce the contact angle. Specifically, a reduction in nanoparticle size and an increase in nanofluid concentration could further reduce the contact angle. However, bare nanoparticles did not change the interfacial tension (IFT). In order to investigate the theory of the structural disjoining pressure (SDP), we extended the model with a configuration that simulates the real case of the detachment of an oil droplet. The results showed that four conditions favor the spreading of the nanofluid on the substrate and the detachment of the oil droplet from the substrate to which it attached due to the structural disjoining pressure (SDP). These conditions include a high nanofluid concentration, a small nanoparticle size, a small contact angle of the nanofluid/oil/substrate system looking from the nanofluid phase, and a large oil droplet. Three imaging experiments were conducted using environmental scanning electron microscopy (ESEM) and dynamic fluid-film interferometry (DFI) to verify the theory of nanofluid spreading due to the structural disjoining pressure (SDP). ESEM imaging experiments showed the result of a single layer of nanoparticles but could not eliminate the effect of evaporation. Combining the ESEM images with the results from DFI in a liquid cell eliminated the evaporation effect and confirmed that nanoparticles are capable of spreading over the substrate in a thin film that is composed of one single layer of nanoparticles. Moreover, an experiment into the extension of the coffee ring effect showed the discovery of a new coffee ring pattern. Finally, we conducted a nanofluid flooding experiment using carbonate rocks. It was able to isolate the effect of the two confirmed mechanisms on the oil recovery rate at core-scale and tested the potential of nano-enhanced oil recovery (nano-EOR) at core-scale. We determined that an increase in oil recovery of 6% was due to the wettability alteration and another 6% increase in oil recovery was due to the mechanism of the structural disjoining pressure (SDP) for our low permeable carbonate core.

Chemical Enhanced Oil Recovery

Chemical Enhanced Oil Recovery PDF Author: Patrizio Raffa
Publisher: Walter de Gruyter GmbH & Co KG
ISBN: 3110640430
Category : Technology & Engineering
Languages : en
Pages : 277

Book Description
This book aims at presenting, describing, and summarizing the latest advances in polymer flooding regarding the chemical synthesis of the EOR agents and the numerical simulation of compositional models in porous media, including a description of the possible applications of nanotechnology acting as a booster of traditional chemical EOR processes. A large part of the world economy depends nowadays on non-renewable energy sources, most of them of fossil origin. Though the search for and the development of newer, greener, and more sustainable sources have been going on for the last decades, humanity is still fossil-fuel dependent. Primary and secondary oil recovery techniques merely produce up to a half of the Original Oil In Place. Enhanced Oil Recovery (EOR) processes are aimed at further increasing this value. Among these, chemical EOR techniques (including polymer flooding) present a great potential in low- and medium-viscosity oilfields. • Describes recent advances in chemical enhanced oil recovery. • Contains detailed description of polymer flooding and nanotechnology as promising boosting tools for EOR. • Includes both experimental and theoretical studies. About the Authors Patrizio Raffa is Assistant Professor at the University of Groningen. He focuses on design and synthesis of new polymeric materials optimized for industrial applications such as EOR, coatings and smart materials. He (co)authored about 40 articles in peer reviewed journals. Pablo Druetta works as lecturer at the University of Groningen (RUG) and as engineering consultant. He received his Ph.D. from RUG in 2018 and has been teaching at a graduate level for 15 years. His research focus lies on computational fluid dynamics (CFD).

Enhanced Oil Recovery Processes

Enhanced Oil Recovery Processes PDF Author: Ariffin Samsuri
Publisher: BoD – Books on Demand
ISBN: 1789851076
Category : Technology & Engineering
Languages : en
Pages : 162

Book Description
Concerned with production decline, shortages of new oil reserves, and increasing world energy demand, the oil sector continues to search for economic and efficient techniques to enhance their oil recovery from the existing oil field using several enhanced oil recovery techniques (EOR)methods. Despite its highefficiency, widely acclaimed potentials, and limitations, the Low Salinity Water Flooding (LSWF), hybrid, and nanotechnology applications have gained vast interest with promising future to increase ultimate oil recovery, tackle operational challenges, reduce environmental damage, and allow the highest feasible recoveries with lower production costs. This synergistic combination has opened new routes for novel materials with fascinating properties. This book aims to provide an overview of EOR technology such as LSWF, hybrid, and nanotechnology applications in EOR processes.

Chemical Nanofluids in Enhanced Oil Recovery

Chemical Nanofluids in Enhanced Oil Recovery PDF Author: Rahul Saha
Publisher: CRC Press
ISBN: 1000433617
Category : Technology & Engineering
Languages : en
Pages : 137

Book Description
Sustainable world economy requires a steady supply of crude oil without any production constraints. Thus, the ever-increasing energy demand of the entire world can be mostly met through the enhanced production from crude oil from existing reservoirs. With the fact that newer reservoirs with large quantities of crude oil could not be explored at a faster pace, it will be inevitable to produce the crude oil from matured reservoirs at an affordable cost. Among alternate technologies, the chemical enhanced oil recovery (EOR) technique has promising potential to recover residual oil from matured reservoirs being subjected to primary and secondary water flooding operations. Due to pertinent complex phenomena that often have a combinatorial role and influence, the implementation of chemical EOR schemes such as alkali/surfactant/polymer flooding and their combinations necessitates upon a fundamental understanding of the potential mechanisms and their influences upon one another and desired response variables. Addressing these issues, the book attempts to provide useful screening criteria, guidelines, and rules of thumb for the identification of process parametric sets (including reservoir characteristics) and response characteristics (such as IFT, adsorption etc.,) that favor alternate chemical EOR systems. Finally, the book highlights the relevance of nanofluid/nanoparticle for conventional and unconventional reservoirs and serves as a needful resource to understand the emerging oil recovery technology. Overall, the volume will be of greater relevance for practicing engineers and consultants that wish to accelerate on field applications of chemical and nano-fluid EOR systems. Further, to those budding engineers that wish to improvise upon their technical know-how, the book will serve as a much-needed repository.

Waterflooding

Waterflooding PDF Author: G. Paul Willhite
Publisher:
ISBN:
Category : Business & Economics
Languages : en
Pages : 358

Book Description
Waterflooding begins with understanding the basic principles of immiscible displacement, then presents a systematic procedure for designing a waterflood.

Nanotechnology for Energy and Environmental Engineering

Nanotechnology for Energy and Environmental Engineering PDF Author: Lalita Ledwani
Publisher: Springer Nature
ISBN: 303033774X
Category : Technology & Engineering
Languages : en
Pages : 605

Book Description
This book examines the potential applications of nanoscience and nanotechnology to promote eco-friendly processes and techniques for energy and environment sustainability. Covering various aspects of both the synthesis and applications of nanoparticles and nanofluids for energy and environmental engineering, its goal is to promote eco-friendly processes and techniques. Accordingly, the book elaborates on the development of reliable, economical, eco-friendly processes through advanced nanoscience and technological research and innovations. Gathering contributions by researchers actively engaged in various domains of nanoscience and technology, it addresses topics such as nanoparticle synthesis (both top-down and bottom-up approaches); applications of nanomaterials, nanosensors and plasma discharge in pollution control; environmental monitoring; agriculture; energy recovery; production enhancement; energy conservation and storage; surface modification of materials for energy storage; fuel cells; pollution mitigation; and CO2 capture and sequestration. Given its scope, the book will be of interest to academics and researchers whose work involves nanotechnology or nanomaterials, especially as applied to energy and/or environmental sustainability engineering. Graduate students in the same areas will also find it a valuable resource.

Modern Chemical Enhanced Oil Recovery

Modern Chemical Enhanced Oil Recovery PDF Author: James J.Sheng
Publisher: Gulf Professional Publishing
ISBN: 0080961630
Category : Technology & Engineering
Languages : en
Pages : 648

Book Description
Crude oil development and production in U.S. oil reservoirs can include up to three distinct phases: primary, secondary, and tertiary (or enhanced) recovery. During primary recovery, the natural pressure of the reservoir or gravity drive oil into the wellbore, combined with artificial lift techniques (such as pumps) which bring the oil to the surface. But only about 10 percent of a reservoir's original oil in place is typically produced during primary recovery. Secondary recovery techniques to the field's productive life generally by injecting water or gas to displace oil and drive it to a production wellbore, resulting in the recovery of 20 to 40 percent of the original oil in place. In the past two decades, major oil companies and research organizations have conducted extensive theoretical and laboratory EOR (enhanced oil recovery) researches, to include validating pilot and field trials relevant to much needed domestic commercial application, while western countries had terminated such endeavours almost completely due to low oil prices. In recent years, oil demand has soared and now these operations have become more desirable. This book is about the recent developments in the area as well as the technology for enhancing oil recovery. The book provides important case studies related to over one hundred EOR pilot and field applications in a variety of oil fields. These case studies focus on practical problems, underlying theoretical and modelling methods, operational parameters (e.g., injected chemical concentration, slug sizes, flooding schemes and well spacing), solutions and sensitivity studies, and performance optimization strategies. The book strikes an ideal balance between theory and practice, and would be invaluable to academicians and oil company practitioners alike. - Updated chemical EOR fundamentals providing clear picture of fundamental concepts - Practical cases with problems and solutions providing practical analogues and experiences - Actual data regarding ranges of operation parameters providing initial design parameters - Step-by-step calculation examples providing practical engineers with convenient procedures

Chemical Enhanced Oil Recovery (cEOR)

Chemical Enhanced Oil Recovery (cEOR) PDF Author: Laura Romero-Zerón
Publisher: BoD – Books on Demand
ISBN: 9535127004
Category : Technology & Engineering
Languages : en
Pages : 204

Book Description
Commercial application of chemical enhanced oil recovery (cEOR) processes is expected to grow significantly over the next decade. Thus, Chemical Enhanced Oil Recovery (cEOR): A Practical Overview offers key knowledge and understanding of cEOR processes using an evidence-based approach intended for a broad audience ranging from field operators, researchers, to reservoir engineers dealing with the development and planning of cEOR field applications. This book is structured into three sections; the first section surveys overall EOR processes. The second section focuses on cEOR processes, while the final section describes the electrorheology technology. These sections are presented using a practical and realistic approach tailored for readers looking to improve their knowledge and understanding of cEOR processes in a nutshell.

Green Synthesis, Characterization and Applications of Nanoparticles

Green Synthesis, Characterization and Applications of Nanoparticles PDF Author: Ashutosh Kumar Shukla
Publisher: Elsevier
ISBN: 0081025807
Category : Technology & Engineering
Languages : en
Pages : 552

Book Description
Green Synthesis, Characterization and Applications of Nanoparticles shows how eco-friendly nanoparticles are engineered and used. In particular, metal nanoparticles, metal oxide nanoparticles and other categories of nanoparticles are discussed. The book outlines a range of methodologies and explores the appropriate use of each. Characterization methods include spectroscopic, microscopic and diffraction methods, but magnetic resonance methods are also included as they can be used to understand the mechanism of nanoparticle synthesis using organisms. Applications covered include targeted drug delivery, water purification and hydrogen generation. This is an important research resource for those wishing to learn more about how eco-efficient nanoparticles can best be used. Theoretical details and mathematical derivations are kept to a necessary minimum to suit the need of interdisciplinary audiences and those who may be relatively new to the field. - Explores recent trends in growth, characterization, properties and applications of nanoparticles - Gives readers an understanding on how they are applied through the use of case studies and examples - Assesses the advantages and disadvantages of a variety of synthesis and characterization techniques for green nanoparticles in different situations

Nanoscale Science and Technology

Nanoscale Science and Technology PDF Author: Robert Kelsall
Publisher: John Wiley & Sons
ISBN: 0470020865
Category : Technology & Engineering
Languages : en
Pages : 472

Book Description
Nanotechnology is a vital new area of research and development addressing the control, modification and fabrication of materials, structures and devices with nanometre precision and the synthesis of such structures into systems of micro- and macroscopic dimensions. Future applications of nanoscale science and technology include motors smaller than the diameter of a human hair and single-celled organisms programmed to fabricate materials with nanometer precision. Miniaturisation has revolutionised the semiconductor industry by making possible inexpensive integrated electronic circuits comprised of devices and wires with sub-micrometer dimensions. These integrated circuits are now ubiquitous, controlling everything from cars to toasters. The next level of miniaturisation, beyond sub-micrometer dimensions into nanoscale dimensions (invisible to the unaided human eye) is a booming area of research and development. This is a very hot area of research with large amounts of venture capital and government funding being invested worldwide, as such Nanoscale Science and Technology has a broad appeal based upon an interdisciplinary approach, covering aspects of physics, chemistry, biology, materials science and electronic engineering. Kelsall et al present a coherent approach to nanoscale sciences, which will be invaluable to graduate level students and researchers and practising engineers and product designers.